1. Acid hydrolysis of cellulosic fibres: Comparison of bleached kraft pulp, dissolving pulps and cotton textile cellulose
- Author
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Harald Brelid, Anna Palme, and Hans Theliander
- Subjects
Paper ,Polymers and Plastics ,02 engineering and technology ,Cellulase ,Cotton ,Hornification ,010402 general chemistry ,01 natural sciences ,Polymerization ,chemistry.chemical_compound ,Hydrolysis ,Polymer chemistry ,Materials Chemistry ,Acid hydrolysis ,Cotton Fiber ,Kraft pulp ,Cellulose ,Dissolving pulp ,biology ,Organic Chemistry ,Hydrogen-Ion Concentration ,021001 nanoscience & nanotechnology ,Pulp and paper industry ,LODP ,0104 chemical sciences ,Molecular Weight ,chemistry ,Kraft process ,Cellulosic ethanol ,biology.protein ,0210 nano-technology ,Kraft paper - Abstract
The behaviour of different cellulosic fibres during acid hydrolysis has been investigated and the levelling-off degree of polymerisation (LODP) has been determined. The study included a bleached kraft pulp (both never-dried and once-dried) and two dissolving pulps (once-dried). Additionally, cotton cellulose from new cotton sheets and sheets discarded after long-time use was studied. Experimental results from the investigation, together with results found in literature, imply that ultrastructural differences between different fibres affect their susceptibility towards acid hydrolysis. Drying of a bleached kraft pulp was found to enhance the rate of acid hydrolysis and also result in a decrease in LODP. This implies that the susceptibility of cellulosic fibres towards acid hydrolysis is affected by drying-induced stresses in the cellulose chains. In cotton cellulose, it was found that use and laundering gave a substantial loss in the degree of polymerisation (DP), but that the LODP was only marginally affected.
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