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Abstract: Non-methane hydrocarbons (NMHCs) are known to have an important role on air quality due to their high reactivity. NMHC analysis has been performed on 148 ambient air samples collected at five different sites in the Kanto area (Tokyo metropolitan area and surrounding six prefectures) of Japan in summer and winter of 2008, and fifty NMHCs have been determined and quantified. A field measurement campaign has been conducted at one of the busiest intersections in Tokyo metropolitan area in winter of 2008. NMHC emissions are evaluated through comparison of distributions of individual NMHCs emitted from motor vehicles, which are estimated from the measurements, with those determined from the current emissions inventory. The comparison revealed that the measured distributions of acetylene, ethylene and toluene showed a good agreement with those estimated from the emissions inventory (the values estimated from the measurements are a factor of 1.5, 0.56 and 2.3 larger than the emissions inventory in median, respectively), however, propane and isobutane are found to be significantly underestimated in the emissions inventory (the measured values were a factor of 18 and 5.1 larger than the emissions inventory, respectively). The significant underestimate of propane can be explained by that the current emissions inventory does not consider emissions from liquefied propane gas (LPG) fueled vehicles. However, for isobutane, reasons for the underestimate are still unclear. Another field measurement has been conducted in summer of 2008, where the air samples have been collected at three different sites on the ground and by a helicopter as well. Remarkable high concentrations of 1-butene and cis- and trans-2-butenes have been sporadically observed in the samples collected at Urayasu in the coastal area of Tokyo bay. Calculated propylene equivalent (PE) concentrations of butenes revealed that those have a significantly important role in ozone formation when the air plume is affected by emissions from their emission sources. The PE concentrations of butenes varied from 0.1 to 39 ppbC, and accounted for 1.5–75% of total PE concentrations at Urayasu. Most of the continuous air quality monitoring stations does not record concentrations of individual hydrocarbons, therefore, the importance of reactive and low concentration hydrocarbon such as butenes might be overlooked in the current emissions inventory and/or air quality model. In this paper, the reliability of NMHC emissions is evaluated based on the field measurements. Their possible impacts on air quality in the Kanto area are discussed as well, based on the calculated propylene equivalent concentrations. [Copyright &y& Elsevier]

This paper analyzes the weekday–weekend differences of ozone, NO x (2) and non-methane hydrocarbons (NMHCs) in Tokyo and Osaka, Japan, from 2001 to 2004, in order to investigate the ozone weekend effect (OWE). Data were measured at 24 and 23 general air monitoring stations in Tokyo and Osaka, respectively. We focused on NO x and NMHCs to investigate the causes of OWE. Specifically, we examined weekday/weekend differences in the titration of O3 by NO and the photochemical ozone production. Weekend ozone concentrations were confirmed to be greater than those of weekdays during most periods in both Tokyo and Osaka, although precursor concentrations were higher on weekdays. Weekday ozone concentrations in Tokyo (other than during 2003) and Osaka decreased due to the reaction of O3 with NO, resulting in higher ozone but lower O x (the sum of O3 and NO2) concentrations on weekends than on weekends. In 2003 in Tokyo, however, the effect of the photochemical ozone production on weekends was larger than on weekdays, as determined by the comparison of ozone concentration increase versus NMHCs/NO x ratio and O x between weekdays and the weekend. The weekend NMHCs/NO x ratio would be in the boundary area between volatile organic compound (VOC)- and NO x -limited regime, so it is considered that the difference between 2003 and the other periods in Tokyo might be due to a change in precursor limitation. [Copyright &y& Elsevier]