1. Characterization of a new composite membrane for point of need paper-based micro-scale microbial fuel cell analytical devices
- Author
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Eduardo Cortón, Diana C. Martínez-Casillas, María Jesús González-Pabón, and Federico Figueredo
- Subjects
Microbial fuel cell ,Bioelectric Energy Sources ,Physiology ,Composite number ,OXYGEN PERMEABILITY ,02 engineering and technology ,TOXICITY SENSOR ,Toxicology ,Pathology and Laboratory Medicine ,01 natural sciences ,Physical Chemistry ,purl.org/becyt/ford/1 [https] ,chemistry.chemical_compound ,Cross-Linking ,Medicine and Health Sciences ,Membrane Electrophysiology ,Anodes ,Separator (electricity) ,WATER ANALYSIS ,Multidisciplinary ,Physics ,purl.org/becyt/ford/1.2 [https] ,021001 nanoscience & nanotechnology ,Electrophysiology ,Chemistry ,Membrane ,Bioassays and Physiological Analysis ,Physical Sciences ,Medicine ,Engineering and Technology ,Protons ,0210 nano-technology ,PEM SUBSTITUTE ,Research Article ,Chemical Elements ,Surface Chemistry ,Vinyl alcohol ,Fabrication ,Materials science ,Science ,PAPER-BASED ANALYTICAL DEVICE ,010402 general chemistry ,Research and Analysis Methods ,Membrane Potential ,Oxygen permeability ,Electrodes ,Nuclear Physics ,Nucleons ,LOW COST MICROBIAL FUEL CELL MEMBRANE ,Chitosan ,Membranes ,Chemical Bonding ,Toxicity ,Electrophysiological Techniques ,Biology and Life Sciences ,0104 chemical sciences ,Anode ,Oxygen ,chemistry ,Chemical engineering ,Polyvinyl Alcohol ,Artificial Membranes ,Electronics - Abstract
Microbial fuel cells (MFCs) can evolve in a viable technology if environmentally sound materials are developed and became available at low cost for these devices. This is especially important not only for the designing of large wastewater treatment systems, but also for the fabrication of low-cost, single-use devices. In this work we synthesized membranes by a simple procedure involving easily-biodegradable and economic materials such as poly (vinyl alcohol) (PVA), chitosan (CS) and the composite PVA:CS. Membranes were chemical and physically characterized and compared to Nafion®. Performance was studied using the membrane as separator in a typical H-Type MFCs showing that PVA:CS membrane outperform Nafion® 4 times (power production) while being 75 times more economic. We found that performance in MFC depends over interactions among several membrane characteristics such as oxygen permeability and ion conductivity. Moreover, we design a paper-based micro-scale MFC, which was used as a toxicity assay using 16 µL samples containing formaldehyde as a model toxicant. The PVA:CS membrane presented here can offer low environmental impact and become a very interesting option for point of need single-use analytical devices, especially in low-income countries where burning is used as disposal method, and toxic fluoride fumes (from Nafion®) can be released to the environment. Fil: Gonzalez Pabon, Maria Jesus. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química Biológica de la Facultad de Ciencias Exactas y Naturales. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química Biológica de la Facultad de Ciencias Exactas y Naturales; Argentina Fil: Figueredo, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química Biológica de la Facultad de Ciencias Exactas y Naturales. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química Biológica de la Facultad de Ciencias Exactas y Naturales; Argentina Fil: Martínez Casillas, Diana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química Biológica de la Facultad de Ciencias Exactas y Naturales. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química Biológica de la Facultad de Ciencias Exactas y Naturales; Argentina Fil: Corton, Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química Biológica de la Facultad de Ciencias Exactas y Naturales. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química Biológica de la Facultad de Ciencias Exactas y Naturales; Argentina
- Published
- 2019