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The occurrence of rockburst can cause significant disasters in underground rock engineering. It is crucial to predict and prevent rockburst in deep tunnels and mines. In this paper, the deficiencies of ensemble learning algorithms in rockburst prediction were investigated. Aiming at these shortages, a novel machine learning model, deep forest, was proposed to predict rockburst risk. The deep forest combines the characteristics of deep learning and ensemble models, which can solve complex problems. To develop the deep forest model for rockburst prediction, 329 real rockburst cases were collected to build a comprehensive database for intelligent analysis. Bayesian optimization was proposed to tune the hyperparameters of the deep forest. As a result, the deep forest model achieved 100% training accuracy and 92.4% testing accuracy, and it has more outstanding capability to forecast rockburst disasters compared to other widely used models (i.e., random forest, boosting tree models, neural network, support vector machine, etc.). The results of sensitivity analysis revealed the impact of variables on rockburst levels and the applicability of deep forest with a few input parameters. Eventually, real cases of rockburst in two gold mines, China, were used for validation purposes while the needed data sets were prepared by field observations and laboratory tests. The promoting results of the developed model during the validation phase confirm that it can be used with a high level of accuracy by practicing engineers for predicting rockburst occurrences. [ABSTRACT FROM AUTHOR]