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With the improvement of environmental protection requirements, paper-making enterprises are imperative to eliminate pollution directly in production. This paper aims to adopt environment-friendly bleaching method, yield good quality pulp products. Op-Pa-P bleaching process of reed displacement cooking pulp is studied in this paper (O-oxygen, P-hydrogen peroxide, Pa-peracetic acid ). The experimental conditions of Op and Pa stage were optimized respectively. It included oxygen pressure, temperature, time in Op stage and charge of peracetic acid, temperature, time in Pa stage. The results show that the optimal technological conditions of Op are: 0.9Mpa, 100°C, 70min, Op stage can make brightness increase by 57.3%, viscosity decrease by 25% and KMnO4 number reduce to 2.6. Pa stage optimal conditions are Pa charge 1.5%, 70°C, 75min, brightness reached to 79.1 %ISO, KMnO4 number to 1.0, viscosity to 631mL.g-1. The brightness of P bleached pulp reached to 84.8%ISO, viscosity 601 mL.g-1, KMnO4 number 0.8.

The total sulfur rate of the coal sample was 4.973%, the inorganic sulfur content was more than 60%, which was the main component in the coal sample. The effect of grinding fineness, flotation pulp density, collector and frother on coal flotation desulfurization were investigated in this paper to remove the inorganic sulfur. The results showed that it reached to the optimum desulfurization rate 54.7% when the optimum grinding fineness was 39.20% -200 mesh rate, pulp concentration was 80 g/L, kerosene consumption was 1.4 kg/t, 2#oil loading was 100 g/t, and the total sulfur content reduced to 2.72%. The optimized flotation condition determined by orthogonal experiments was as follow: pulp density for 60 g/L, kerosene dosage of 1.4 kg/t, 2#oil consumption of 100 g/t. In this case, total sulfur content reduced to 2.19%, the total desulfurization rate and the inorganic desulfurization rate were 55.96% and 92.89%, respectively.

For the conversion of cellulose into biofuel by microorganisms is being studied intensively. This research isolate and screen efficient cellulolytic microorganism from bamboo forest soil based on growth rate on CMC plate, the size of transparent circle, disintegration effect of filter paper, and CMC enzyme activity assay. As a result, efficient cellulose-decomposing fungus J6-1 was obtained. The strains possessed higher filter paper degrading ability and CMC enzyme activity, disintegrating the filter paper into 42.3% at the 5th days and reaching the highest CMC enzyme activity 6.87IU/mL after 120 hours of shake flask fermentation. Strains J6-1 is preliminarily identified asPenicilliumby morphological observation and a great potential cellulolytic strains.

This paper describes the method of treating wheat straw pulp black liquor with microwave radiation. The granular activated carbon and CuO are used as a catalyst.Effects of effective factors such as the total amount, ratio, microwave power, time on treating process are studied. The reaction mechanism is also researched. The results indicate that the oxidative decomposition process of lignin or organic pollutants is combined action of activated carbon and CuO absorption-degradation with microwave induced oxidization. This approach is easy to operate, quickly to treat, completely to react and no new pollutants. So it is used to treat black liquor of containing organic pollutes which is hardly degraded.

In order to optimize the regeneration conditions of cation exchange resin, the paper based on the actual data of production, the cation exchange resin regeneration condition was optimized by the process of mathematical modeling, which achieved good results. Research showed that reducing regeneration acid feeding time could effectively reduce the consumption. It could reduce the production cost and make enterprises obtain more economic benefits. Calculated and measured were agreed showed that the study and calculation on regeneration of cation bed were accord with actual production, and had practical value for ion regeneration process. Through least square fitting showed that the 80min was the best acid feeding time, acid consumption of unit volume of water was the lowest.

This paper aims to study the effect of using Oxidized White Liquor (OWL) on pulp brightness in peroxide bleaching. The proper setting of the concentration of hydrogen peroxide, the bleaching temperature, and the bleaching time was also studied. The Central Composite Design (CCD) was proposed to generate necessary experimental runs. Regression analysis was used to determine the relationship equation. Optimization helped determine that to obtain the targeted brightness of 83%, the ratio between the volume of OWL and sodium hydroxide should be 50:50. This ratio should be used with a concentration of hydrogen peroxide at 6.9 g/kg, a bleaching temperature of 90 oC and a bleaching time of 75 minutes.

Recovery and use of secondary fiber for paper production is increasing all over the word. In recovered paper recycling, stickies are the most detrimental among the contaminants, affecting both the process efficiency and the quality of the final product. In this study, StickAway enzyme was used to treat the old newspaper(ONP) pulps. The effect of enzymatic treatment on the macro and micro-stickies, the drainage property, as well as the formation of paper products were investigated. After treatment of samples with 3LU/g (o.d pulp) doses of enzymatic for 1.5 h, it was found that 14.6% of the micro-stickies could be removed. The cationic demand, turbidity value and particle size were decreased 7.23%, 14.4% and 6.02% respectively compared the control sample. Furthermore, enzymatic treatment also improved the drainage properties of pulp slurry and the formation of paper products. Results confirmed that under the optimal conditions, the StickAway enzyme show the excellent performance in the treatment of the stickies of recovered pulps.

The lignin removal of pulping process is left in black liquor, and with relation to the paper pulp lignin. The higher the black liquor lignin content is, the bigger the lignin of paper pulp is removed. This paper analyzes the delignification mechanism of wheat straw atmospheric pressure pulping with microwave radiation. The relations of black liquor lignin content and alkali concentration to pulping time are described in detail. The results show that delignification process is divided into two stages: quick stage and residual stage. The lignin removal rate in the first stage is much higher than the second stage, that is, lignin has been removed more sufficiently after quick stage. In first stage, reaction order of delignification is 1.0, and 0.7 with respect to OH-, the activation energy is 38.62 kJ • mol-1. The latter delignification also belongs to the first-order reaction and 4.4 with respect to OH-, the activation energy is 75.56 kJ • mol-1. Apparently, residual stage needs to consume large amounts of energy to removal lignin.

Poplar P-RC APMP was chosen as raw materials for fines generation and collecting, and then the P-RC APMP fines and calcium carbonate were co-flocculated before they were added into fiber fraction to make fine paper. Effect of different sub-fractions P-RC APMP fines and dosage of fines to make fine paper were studied. The result showed that, with the increasing of different sub-fractions fines dosage, the whiteness of paper increased first then decreased. For 200-mesh fines, 300-mesh fines, 400-mesh fines, the highest whiteness are obtained at 10%, 15%, 10% dosage respectively. Adding fines has positive effect on strength properties of paper. With the increasing of fines dosage, the strength properties of paper increased. Besides, the order of paper whiteness and strength is 400-mesh >300-mesh >200-mesh when using the dosage is same.

Both qualitative and quantitative effect of TiO2 suspension presence in cigarette filter have been analyzed in order to reduce harmful substances in cigarette smoke, optimizing the capability of TiO2 suspension as nano filter in cigarette filters and reviewing the analysis in order to obtain results with the best variation. Samples in the form of filter paper that has passed of the smoke with some variation treatment as it become ready to be tested and analyzed. Parameter such as concentration and volume variation of TiO2 suspension, and also the inputting method of TiO2 suspension into cigarette filter. Samples were characterized using FT-IR spectrophotometer and samples data absorbance obtained in each catchment area. The results showed that by reducing absorbance value percentage of each catchment area, with inputting method of TiO2 suspension through the cigarette filter tip and base, it appears that the most stable and lowest reduction present in C3 and H3, which is sample with 1.85 mol/liter concentration and 0.3 ml suspension volume. Both sample reduced particulate matters significantly after confirmed with X-Ray Fluorescence and SEM-EDS results, and was compared to sample filter without TiO2. Inputting method of TiO2 suspension through a base of cigarette butt is better and safer than through end of cigarette filter.

The manufacturing of furniture using rattan is becoming common nowadays, and creates high amount of waste that can be value-added into binderless particleboards (BPB). In order to determine the suitability of the rattan waste for production of BPB, characterization of rattan waste is executed and reported in this paper. The physical properties such as density and moisture content of the rattan waste, together with its morphological study and thermal analysis as well as lignin content are evaluated. It is observed that density and moisture content for rattan waste are in the range of 0.64g/cm3, and 11.3% respectively. On the other hand, the morphology of rattan stem showed that rattan waste has various diameters of vascular bundles along with wide metaxylem vessels as well as thin-walled fibres. Thermal analysis of rattan waste explicated that rattan waste went through endothermic process with peak melting point of 177.80 °C during heating. The greatest weight loss occurred at 257.03 °C. Rattan waste has high lignin content of 21.2% that obtained through Klason lignin test. These promising preliminary results show that the rattan waste is appropriate to be used as raw materials in producing BPB.

Lignin is the second most abundant naturally occurring macromolecule found in plant cell-wall, vascular components and woody stems. It is the largest renewable source of aromatic biopolymer. However, lignin is recalcitrant to be broken down by most chemicals. This is because of its complicated heterogeneous molecular structure. However, lignin depolymerization has huge potentials for the synthesis of a number of useful chemicals, perfumes and pharmaceuticals and toiletries. The oxidation products of lignin are important precursors for pulp/paper and food industries, synthetic thin films. Vanillin, veratryl aldehyde and para-benzoquinone are the oxidation products of lignin. These chemicals are the precursors of optically active alcohol, ketone, violuric acid and benzaldehyde. However, the oxidation of biolignin has been remaining a challenging task. Green catalytic approaches might be an interesting solution for the selective depolymerization of lignin into various platform chemicals. Metal oxide/silica supported nanoporous gold has received strong attention as green catalyst for the transformation of various natural polymers. Mesoporous metal oxide/silica provide enlarged surfaces for the breakdown of C-C, C-H and C-OH bonds. This paper has reviewed various green catalytic approaches for the control depolymerization of biolignin into platform chemicals.

In the process of recycling phosphate ore processing wastewater, the accumulation of inorganic ions and the flotation reagents have a great influence on the flotation performance when they reach to a certain concentration. This paper studied the effect of Ca2+, Mg2+, SO42- and PO43- on the reverse flotation of phosphate ore through the single factor experiment. The experimental results show that Ca2+, Mg2+ and PO43- have less effect on the flotation performance, and that a certain amount of PO43- in the ore pulp can reduce the dosage of acid and improve the flotation result. SO42- has a significant effect on the reverse flotation of phosphate ore and the concentration of SO42- should be controlled under 1 g/L in the backwater utilization.

To observe binder distribution, and obtain the relationship between drying method and binder distribution in the z-direction, Rhodamine B was used to stain the binder and as the probe to characterize z-directional distribution of the binder using LSCM. The results implied that it was reliable and effective method using LSCM to characterize the z-directional distribution of binder and analyze the influence of dry method on binder migration. It could be concluded that the dry method was critical to binder distribution in coated paper and vacuum drying accelerated binder migration to the base paper, however vacuum drying made uniform binder distribution. Infrared drying was good to producing little binder migration towards the interior of base paper, but infrared drying was disadvantageous to even binder distribution.

This study obtained 12 microbial degradation of cellulose from perennial accumulation of cellulose waste soil, through Congo red staining, isolated high efficient bacteria N4 degradation of cellulose. The N4 strain degradation single factor experiment showed that: carbon concentration, incubation temperature and initial pH value influence on the degradation of filter paper. Through the orthogonal experimental study obtained: when the concentration of filter paper is 0.5%, culture temperature is 30 °C, initial pH is 8, N4 strain filter paper degradation rate reached optimal, filter paper weight loss rate of 68.92%.

The main materials of artificial fiber pulp are natural fiber from wood and linters etc. However, it will be more and more difficult to make this pulp in China because of the scarcity of forest resource and cotton field. Reed is widely distributed with high yield in china. Therefore, exploitation and utilization of reed in artificial fiber pulping have an important social significance. The artificial pulp made from reed was studied in this paper. The pulping method adopted pre-hydrolysis followed by Kraft cooking. The results showed that the great influence factors of pre-hydrolysis were the highest temperature and holding time. The optimal pre-hydrolysis conditions were: 175 °C, 75min, solid-to-liquid ratio 1:6. Under the conditions, semi-slurry yield was 60.8%. Compared with the chemical composition of reed materials, the pentosan decreased from 20.33% to 7.37%, the lignin decreased from 26.46% to 21.14%, ash decreased from 5.56% to 4.05%, besides the relative holocellulose increased from 75.95% to 81.26%. The dissolving pulp obtained after cooking and bleaching of semi-slurry met with pulp performance index requirement.

Because of the coating binder migration in cross-section of coating layer, the binder concentration will be different in z-direction of coating layer, which affect some properties of coated paper. The Paper studied the effects of pigment type, coating color solid content and dying temperature on binder migration and affected factors. The z-direction distribution of the coating binder which was tagged with Br in coating layer and its concentration in coating surface were examined quantitatively by using SEM-EDXA and ESCA analysis. The mechanism of binder migration was also proposed. The results indicated that the degree of binder migration is directly proportional to the drying temperature, that the increase of the ratio of calcium carbonate in the pigment content, coating surface binder concentration increased. The result also indicated that the degree of binder migration was increased with reduced the coating solid content.

This paper studied the differences of pulping performances, beating characteristics and strength properties between green liquor pretreatment-Kraft pulping and conventional Kraft pulping based on previous optimized pulping conditions. The green liquor pretreatment-Kraft pulping has higher yield, lower Kappa number, reduced residual effective alkali and decreased viscosity. Green liquor pretreatment improves pulp strength properties although green liquor pretreatment-Kraft pulp has beating characteristics similar to conventional Kraft pulp.

Six dominant thermophilic cellulolytic bacteria were separated from undigested dewatered sludge. By analysis of their water content, value of hydrolysis up, rate of weight loss of filter paper and CMC-enzyme activity, a dominant thermophilic cellulolytic bacterium named XW5was separated and inoculated in the dewatered sludge under simulating bio-drying conditions. The results showed that water content of the dewatered sludge which was inoculated dominant bacterium was decreased from an initial 70.05% to 62.49%.

This study aimed to analyze the kinetics of enzymatic hydrolysis of cellulose. Cellulase enzyme was obtained fromAspergillusnigergrown on filter paper and the hydrolysis process was carried out in solid state. The kinetic reviewed here was the relationship between glucose production and cellulose mass reduction to optimize the parameters of Monod equation at various moisture levels.

Based on the requirements of sustainable development and innovative design concept, Al films deposited by DC magnetron sputtering solves the paper based Al film forming technology of aluminum plated corrugated cardboard material so as to obtain new environmental protection. To explore the combination design, aluminum plated corrugated cardboard furniture design idea and concept of aluminum plated corrugated cardboard and other materials of the modular design, promotes the application and practical popularization value. The production of functional strong, stylish new aluminum plated corrugated cardboard furniture, can meet the needs of a growing social material production and life.

This document demonstrates how to affect the brightness of liquid package recycled pulp by hydrogen peroxide bleaching and FAS beaching. The optimum H2O2 bleaching process conditions: 8% H2O2, 4% NaOH, bleaching temperature 80 °C, bleaching time 1.5h. The best FAS bleaching conditions was FAS dosage of 0.5%, NaOH dosage of 0.25%, bleaching temperature at 80 °C, time for 30min. And bleaching had no adverse effect on the performance of bleached pulp fiber.

Using novel dual cathode/electro/Fe2+/S2O82-system to treat pickle sauerkraut wastewater, the paper investigates the influencing factors (S2O82-dosage, Fe2 +dosage, current density, Wastewater pH, electrode plate distance) of the organic matters removal and the treatment effect. Test results show that the degree of various factors influence on COD removal of sauerkraut wastewater is different. The COD removal is little effected by pH, while largely effected by current density, dosage of Fe2 +and S2O82-dosage. Under the optimum experiment conditions, current density for 30mA/cm-2, dosage of Fe2 +for 8mmol/L, S2O82-dosage for 12 mmol/L, electrode plate distance for 2 cm and pH=6, sixty minutes electrolysis, wastewater removal rate reach up to 92.6%. These results suggest that this electrochemical oxidation process by dual cathode/electro-Fe2+-S2O82-system might provide an alternative for the degradation of pickle sauerkraut wastewater.

Sludge Concentration (MLSS) is one of major parameters for operation of Anoxic/Aerobic-Membrane Bioreactors（A/O-MBR）and it influences the removal efficiency of pollutants and the rate of membrane fouling as well. This paper focuses on the effects of different MLSS on the treatment of domestic wastewater, the quantity and composition of extracellular polymeric substance (EPS), and the variation of the rate of membrane fouling. It also includes a preliminary analysis of the correlation between EPS and membrane fouling to provide reference for future studies of the mechanism of membrane fouling.

In this research, the laccase mediator system (LMS) was used to modify the unbleached triploid populus tomentosa alkaline hydrogen peroxide pulp (APMP). The changes of pulp brightness were measured and the effects of LMS on the subsequent hydrogen peroxide bleaching were also determined. Besides, the fiber morphology was analyzed by ESEM, and then the obvious changes of pulp have been recovered. In a word, the LMS has obvious effect on cellulose.

This paper made the detailed discourse for the study on using cellulase, hemicellulase hydrolysis of poplar fiber raw material to make glucose. The raw material used in this experiment is poplar, cellulase and hemicellulase enzymes are used. Hemicellulase is a complex system, xylose is regarded as the main chain for a lot of hemicellulose. The experiment used dry poplar as raw material, through the ball mill, ground poplar into wood powder. In the experiment, the optimal condition of enzyme hydrolysis of wood powder has been discussed based on reaction temperature, reaction time, enzyme concentration, and the pH value of reaction. Finally, under the optimal condition, use enzyme to hydrolyse wood powder, measure reducing sugar content by the DNS method, and calculate the rate of hydrolysis.

In this paper, synthesis and fluorescence performance of graphene oxide have been primarily studied. Fistly, graphene oxide with remarkable fluorescence performance was prepared by modified hummer’s method. Secondly, changing the reaction time, the structure and size of graphene oxide were analyzed using X-ray diffraction (XRD) and Malvern Zeta-Size Analyzer, and the effects of different reaction conditions on the XRD patterns of graphene oxide were discussed. Finally, the fluorescence performance of graphene oxide solution were analyzed using fluorescence spectrometer.

The Polyacrylamide (PAM) is a frequently used flocculant for high concentration suspensions removal in water treatment characterized by the generation of large and dense flocs. In this paper, by using the anionic PAM as flocculant, a full-scale experimental study was carried out on flocculating ferric flocs sludge with pelleting flocculation blanket process under scale of 19~38 m3/h. The investigation aimed to optimum the dosage of the PAM and evaluate the application of the PAM in ferric flocs sludge treatment. The experimental results indicated that the increasing of PAM dosage could improve both outlet turbidity and thicken sludge concentration obviously, under the raw wastes concentration of 285~1022 mg/L, the system could achieve ideal operation effect with PAM dosage of 0.3~2.7 mg/L and treatment unit surface loading of 19~38 m3/m2·H. The investigation results also proved that there exists an approximately linear relationship between optimal PAM dosage and raw sludge concentration, that is, the increasing of raw sludge concentration would require synchronously rising of the optimal dosage. While the relationship between maximum surface loading and raw sludge concentration appeared negatively linear dependence, the maximum surface loading would decreased linearly with the increasing of inlet sludge concentration.

Delignification of banana peel, agricultural waste, is considered in the pulp production because lignin is a major obstacle to the gain of cellulose. The soda process as a conventional method and micro-morphology observed by scanning electron microscopy were fulfilled to investigate an optimal condition in this study. The results pointed the potent sequence of operating factors was delignification temperature > solid-liquid ratio > soda concentration > time. The removal of lignin could achieve 92% under the optimal condition using 12%w soda concentration with 1:8 solid-liquid ratio at 100°C for 40 min. This shows that the alkaline delignification is productively sufficient for the pulp production.

This paper mainly researched on preparation and the setting time of Magnesium Phosphate Cement (MPC). The method of orthogonal experiment was adapted to determine the best ratio of MPC, and change the content and types of the material according to the influence of various factors, so as to get the longer setting time of MPC. The results showed that, when the water cement ratio is 0.12, the factors significantly influencing the setting time is magnesium phosphorus ratio (M/P), fly ash and borax. The optimal mixture ratio was obtained through the orthogonal analysis, namely M/P is 3/1, borax content is 16%, and the amount of fly ash is 40%. When M/P is 1/1 and 2/2, borax content is not more than 22%, and the amount of fly ash was less than 60%, the longer setting time of MPC can be produced.

Coal gasification wastewater, as a typical industrial wastewater has poor biodegradability and high toxicity. In this paper, simple anaerobic shaker test was conducted to investigate the degradation of hydroquinone in coal gasification wastewater. Anaerobic sludge shaker test were run for 27, 50 and 73 days, the phenol concentration were adjusted to 300 mg/L and 500 mg/L with pH 7.5, respectively. The experimental results also showed that this system could effectively deal with COD and phenol removal and remain in a stable level when the operational parameters altered while the hydrolysis acidification at 45h is appropriate. Organics degradation and transformation of anaerobic coal gasification wastewater samples at 12h, 24h, 36h, 48h, and 60h were analyzed by GC/MS and it was found that hydrolysis acidification played an important role in degradation of methyl phenol, hydroquinone and refractory compounds. Therefore, the results illustrated that the simple anaerobic shaker process is an easy way for pollutant degradation and treat coal gasification wastewater effectively.

This paper studied effect of different pretreatment process on Yunnan phosphorus building gypsum strength and crystal morphology such as washing method, lime neutralization method, flotation method and Hans method. A lots experiment result indicated that basic properties of phosphorus building gypsum of different pretreatment methods could satisfy related building materials products technology requirements. While inorganic impurities could be effectively removed by lime neutralization method and washing method, as well as organics could be better removed by flotation method, however, compared with other methods, the Hans method possessed the best effect about removing soluble phosphorus, fluorine and organic compounds in phosphogypsum , and had other benefit such as low cost, easy operated and high strength.

This paper presents a comparative evaluation of three lignocellulosic residues (coffee husks, spent coffee grounds and pequi husks) as precursor materials in the production of activated carbons (ACs). Results indicate that the precursor material has a significant effect in both physical and chemical aspects of the adsorbent, with the AC based on spent coffee grounds being the most effective for phenol removal, with maximum adsorption capacity comparable to commercial ACs.

Nowadays the traditional dyeing wastewater treatments based on flocculation-biochemical technology become more difficult than before. The study in this paper aim was it to probe how adding rare earths (REs) into iron-carbon micro-electrolysis process to advance dyeing wastewater degradation. Firstly, the principle was discussed. Then the experimental methods were stated and it followed by exploring effect of iron powder size on the dye decolorization rate. Next were design of the micro electrolysis orthogonal experiments and discussion of influences of related factors on waste water treatment. The experimental results show that besides common iron powder particle size and the processing time, the factors that have great influence on dyeing wastewater treatment are Ce4+, pH, La3+ and iron/carbon ratio. The sequence of factors influence on wastewater micro-electrolysis treatment is Ce4+ > pH > La3+ > iron/carbon ratio. When pH is 6, COD removal rate arrives at maximum 89%, however when the pH is in the case of too high or too low, the effect of sewage degradation is not good.

Ethanol is a kind of basic biomass liquid energy , the conversion of biomass to ethanol has been studied extensively. The process of biomass pretreatment can change its physical and chemical properties, and these changes affect the chemical conversion of biomass products in quality and yield of late. This paper reviews the physical method, chemical method, biological method, three kinds of pretreatment technique, the related principle and development prospects are introduced.

In recent years, with the excellent mechanical properties, good thermal conductivity and electrical conductivity and optical properties, Graphene is widely used in many fields such as chemistry, physics and material science .The preparation of graphene have had a very big progress.This paper reviews the chemical preparation methods of graphene and the application of Graphene / Chitosan composite.Then we point out the outlook of the application of the composite materials graphene with other biological macromolecules which are similar with chitosan.

Composites with the chopped segments of lower part of rice straw (LRSS) as main constituent, poly (vinyl alcohol) (PVA) as adhesive constituent and waste paper (WP) as enhancing constituent were prepared by hot-pressing method. WP showed good enhancing role and certain toughening effect. WP made tensile strength increase by 86% and strength at tensile break by 69%; when composites were prepared at 40% PVA content, 140°C for 10 min. The tensile stretch and stretch at maximum tensile force of WP enhanced composite were respectively 16.5% and 14.3%, while those were respectively 12.3% and 11.9% without WP. The tensile strength of the composites increased with increasing PVA content. From 20% PVA content to 50% PVA content, tensile strength increased by 42.8%. When PVA content was 50%, the composite reached its maximum strength of 8.71 MPa. The hardness of composites lay between 91 and 97.

This paper deals with the advanced oxidation using Electro-fenton reagent for the degradation of azo-dyes in textile effluents. Discharge of textile effluents causes inevitable pollution of water resources which calls for further treatment methods. In this experiment, textile effluent samples were treated with iron electrodes with the reagents, hydrogen peroxide and ferrous sulfate .The acid dye effluents which were used in this study are Acid Orange 7, Acid Red 88, and Acid Violet 7. The temperature was set to 40° C. Samples of 20 ml were analyzed for Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD) and Colour reduction. Experiments were carried out at voltage variations of 2, 4, 6 and 8 volts. From the results, COD and Colour were observed to be reduced drastically from respective original values before treatment with Fenton’s reagent using electro-chemical method.Keywords--- Advanced oxidation, Electro-fenton, BOD, COD, Colour reduction

Sewage sludge is difficult to degrade in anaerobic digestion systems and pretreatments have been shown to speed up the hydrolysis stage. In this paper sludge anaerobic digestion experiments with peracetic acid as a pretreatment were carried out and the effects of acid pretreatment using peracetic acid on subsequent digestion were investigated. It has been proved that this treatment effectively leads to a solubilisation of organic material and thus leads to a increase of soluble chemical oxygen demand (SCOD) and volatile fatty acids (VFA) concentration. Besides, the SV of sludge was reduced and the settling characteristics of sludge were improved. But high dosage of peracetic acid lead to a decrease in biogas production and the proper dosage was 20 g/kg DS. It can be concluded that sludge anaerobic digestion with peracetic acid pretreatment is an effective method for biomass material transformation.

A lignin-degrading bacterium was isolated on mineral salt medium amended by lignosulfonate (L-MSM) agar from the activated sludge of a pulp and paper mill wastewater treatment plant and identified as Sphingobacterium sp. HY-H by biochemical tests and 16S rRNA gene sequencing. The maximum kraft lignin (KL) degradation capability of strain HY-H was determined to be 28.2% on a COD basis under the optimal conditions of pH 7.0, temperature 30°C, and KL to nitrogen (as NH4Cl) ratio of 2 by mass. Moreover, growth kinetic studies showed the KL tolerance of strain HY-H was relatively high and the analysis of KL degradation products by GC-MS revealed the formation of low-molecular-weight aromatic compounds (LMWACs), such as guaiacol, vanillin and vanillyl alcohol, indicating that the strain HY-H can oxidize guaiacyl (G) units and syringyl (S) units in lignin structure. In addition, some low molecular ketone compounds such as 4-hydroxy-2-butanone and methyl vinyl ketone were detected in the inoculated sample after 48h, further validating the partial but possible degradation of KL by strain HY-H.

A novel kind of environmentally friendly composite materials containing upper part of rice straw segments (URSS), poly (vinyl alcohol) (PVA) and waste paper (WP) were prepared by hot-pressing at 140°C for 10 min. The tensile strength, tensile elongation and hardness of composites were measured. Results showed that the tensile strength and the strength at tensile break of the composites first increased and then decreased with increasing PVA content. Tensile strength was higher than the strength at tensile break at different PVA contents, indicating that URSS/PVA/WP composite materials had certain toughness. Otherwise, URSS/PVA/WP composite materials had higher tensile strength than URSS/PVA composites. The tensile strengths of them were respectively 9.25 MPa and 3.9 MPa when prepared at PVA content of 40%. The hardness of composites lay between 90 and 96. Negligible difference exists in every composite.

Aiming at the difficulty of treating dyeing wastewater, the limitation of the traditional electrolysis method, the high cost of active carbon and the environmental pollution of the chicken manure in farms, the paper put forward a new method of using iron combined with biological carbon derived from chicken manure forming internal electrolysis to treat dyeing wastewater. It discussed the effects of mass ratio of iron and biological carbon derived from chicken manure, pH, reaction time, the particle size of iron filings, the aeration rate, circulation velocity and the circling liquid volume on the removal rate of the organic matter in wastewater. The result showed that iron combined with biological carbon derived from chicken manure forming internal electrolysis to treat dyeing wastewater could "using waste to treat waste" and the effect was better. The removal rate of COD was over 85% and the decolorization rate was over 95% when the mass ratio of iron and biological carbon derived from chicken manure was 1:1, the PH was 6, reaction time was was 60min, the particle size of iron filings was 0.9~2.0mm, the aeration rate was 10mL/min, circulation velocity was 50r/min and the circling liquid volume was 2000mL.

The essence of the two phase anaerobic biological treatment process is to place acid bacteria and methane-producing bacteria in two reactors respectively, where it can provide the optimal conditions for their growth and metabolism, allowing them to live up to their maximal activity, which greatly improve processing capacity and efficiency compared to a single-phase anaerobic digestion. The paper start with the two phase anaerobic digestion process, in order to discuss the development direction of high efficient anaerobic digestion system.

The paper introduced a new idea of culturing Chlorella with combined reverse osmosis (RO) brine concentrate and primary effluent from sewage treatment plant as culture medium. This method was expected to reuse wastewater resource and lower the cost of Chlorella cultivation. The biomass of Chlorella at different temperature and different proportion of RO brine (0-90% by volume) were measured. Results showed that Chlorella had an ability to grow in RO brine blended with primary effluent. The biomass of Chlorella in 30% of RO brine blended was the most. At a low temperature of 10℃, the effect of RO brine on Chlorella biomass was obvious, high temperature (30℃) inhibited the growth of Chlorella, 20℃ was the most favorable temperature for growth.

In this paper, the pyrolysis characteristics ofChlorella vulgaris(C. vulgaris) (a kind of microalgae) under different microwave power and pyrolysis atmosphere are studied by microwave oven. The results show that under N2atmosphere, a power of 1500W is required for optimal oil production, 2250W for optimal gas production and 750W for optimal residue. Under CO2atmosphere, a power of 2250W is required for maximum oil production, 1500W for maximum gas production and 750W for maximum residue.

Xylanase is effective and specificity to xylose catalytic degradation, and has strong adaptability. In this paper, effect of xylanase treatment on the drainge and physical properties of high yield pulp was studied. The results showed that, compared with the untreated high yield pulp .The brightness of the treated pulp increased 1.84 %ISO, light scattering coefficient alse increased, opacity coefficient decreased. Tearing index, breaking length and bursting index respectively increased by 15.7%,9.07% and 14.85%.

As textile industrial and glass paper-making materials, dissolving pulps are scarce in China and a great deal of dissolving pulps are imported in the recent years. Currently different fiber materials are tried to produce dissolving pulp in China. In this research work the hydrolysis parameters of the fast-growing poplar based dissolving pulp producing were investigated .And the chemical composition of pulp after hydrolysis were also analyzed, the experimental results showed that the optimal hydrolysis conditions were acid dosage in the range from 0.015% to 0.035%, wood-to-liquor ratio 1:6.5, and the temperature 130 °C. The pentosan content of the pulp after hydrolysis in this hydrolysis conditions was in range of 0.62%-23.16%, which decreased by 23.01%. And the cellulose content slightly changed.

In this paper, mechanisms and defiberation point of Dendrocalamus Giganteus Munro kraft pulping were studied. The results showed that the delignification of kraft cooking could be divided into 3 stages: the bulk delignification stage, which was from the beginning of heating to 165°C for 30min, and its delignification rate was above 80%; the supplementary deligninfication stage, which was from 165°C for 30min to 90min, and about 11% of lignin was dissolved in this stage; the residual delignification stage, which was from 165°C for 90min to the end of cooking, and about 1% of lignin was dissolved in this stage. And the defiberation point during kraft cooking was at 165°C for 60min nearby.

The electrochemically mediated delignification of pulp fibers is one of the promising bleaching methods, which can give the delignified pulp with good subsequent bleachability and high pulp viscosity. Our previous work has shown that the poplar kraft pulp can be delignified to 45% delignification ratio with less than 10% pulp viscosity loss at the condition of 1% pulp consistency which limits the application of this method in pulp industry. The high-consistency electrochemical delignification of poplar kraft pulp was investigated in this paper. The delignification ratio, pulp viscosity loss and brightness were measured as well as the delignification conditions, such as pulp consistency, voltage of electrolysis cell, temperature, circulation of electrolysis liquor and time, were discussed. The results showed that at the 10% pulp consistency, the circulation of electrolysis liquor between pulp cell and electrolysis cell can efficiently improve the delignification ratio, and the pulp viscosity loss is less than 10%. The subsequent bleachability for H2O2 is similar as that of 1% consistency delignified pulp. The pulp also can be bleached to higher than 80% ISO with following EP stage at 2.5% H2O2 dosage.

N,N-dimethyl twelve/fourteen quaternary ammonium DSD acid-1,3,5-triazine derivatives containing three-component were prepared through three-step condensation reaction using inexpensive twelve/fourteen tertiary amines as raw materials. The obtained products were confirmed by UV and IR spectrum. The maximum UV absorptions of 5a-i were in the range of 250-350 nm. The absorption peaks of cis- and trans- isomers were in 272-274 nm and 326-328 nm, respectively. The maximum fluorescence emission peaks of the products located in the range of 428-430 nm. The physical properties of the products were performed by whiteness measurement. The results show that the nine products have obvious effect on the filter paper whiteness. In particular, the product 5e have the best effect on the filter paper whiteness at a concentration of 1.6 (o.w.f %), which the value of whiteness is 96.78.