713 results
Search Results
102. The Influence of Crystallization on the Ionic Conductivity of PEO/LiClO4 Polymer Electrolytes
- Author
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Qiong Zhou, Xiao Can Zhang, Gui Wu Lu, and Yu Feng Wang
- Subjects
Materials science ,General Engineering ,chemistry.chemical_element ,Electrolyte ,Lithium perchlorate ,Amorphous solid ,law.invention ,Crystallinity ,chemistry.chemical_compound ,Chemical engineering ,chemistry ,law ,Phase (matter) ,Polymer chemistry ,Ionic conductivity ,Lithium ,Crystallization - Abstract
It’s generally accepted that the transport of lithium ions in solid polymer electrolytes exists mainly in the amorphous regions, thus the research has focused on reducing the crystallinity to obtain high conductivity at room temperature. However, the point has been challenged: crystalline systems can provide a better ionic conductivity. In this paper, PEO/LiClO4polymer electrolytes with different lithium-oxygen ratios were prepared by melt-blending. The results show that [EO]/ [Li+] = 3 system has higher ionic conductivity, 4.26×10-6S/cm, more than twice as that of [EO]/ [Li+] = 4 system. DSC and XRD results show PEO3:LiClO4crystalline phase present in both systems, the crystallinity of [EO]/ [Li+] = 3 system is higher. It illustrates the generally accepted mechanism is not suitable for these systems, suggesting the high conductivity of [EO]/ [Li+] = 3 system is due to the unique crystal structure of PEO3:LiClO4. Besides, as the crystallinity increases, the tensile strength of [EO]/ [Li+] = 3 system increases greatly, to 1.43 MPa. In addition, because of the high melt temperature of PEO3:LiClO4, the electrolytes will gain excellent heat resistance. In summary, this paper provides a new idea to prepare polymer electrolytes with high ionic conductivity, improved strength and excellent heat resistance in large scale.
- Published
- 2015
103. Studies of Reaction Kinetics of Catalytic Hydrogenation of Isophthalonitrile for Meta-Xylenediamine Preparation
- Author
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Yu Gang Li and Ling Qi Kong
- Subjects
Solvent ,Chemical kinetics ,chemistry.chemical_compound ,Aniline ,chemistry ,Inorganic chemistry ,General Engineering ,Organic chemistry ,Xylenediamine ,Raney nickel ,Catalytic hydrogenation ,Bar (unit) ,Catalysis - Abstract
With Raney nickel catalyst and aniline solvent, the reaction kinetics of catalytic hydrogenation of isophthalonitrile (IPN) for meta-xylenediamine (MXDA) preparation is studied in this paper. The experiment is conducted in a 1L büchiglas high-pressure hydrogenation reactor under the condition of the reaction temperature (100°C) and the reaction pressure (35 bar). The results shows that the kinetics equation proposed in this paper can be used to predict the response speed of IPN accurately.
- Published
- 2015
104. Mathematical Model of Pressure and Flow Distribution on Fluorine Production Lines
- Author
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Oksana P. Kabrysheva, Oleg P. Savitsky, and Valeriy F. Dyadik
- Subjects
Production line ,Mathematical optimization ,chemistry ,Computer science ,business.industry ,Flow distribution ,General Engineering ,Fluorine ,chemistry.chemical_element ,business ,Automation ,Simulation - Abstract
This paper is devoted to one of the most urgent problems in the automation of fluorine production (FP) processes: the development of a dynamic model of the hydrodynamic regime. The paper suggests a dynamic model represented in the form that provides the effective use of up-to-date methods of synthesis and analysis for control algorithms. The model is a set of dynamic models of individual units and devices that have a significant impact on the processes in the technological scheme.
- Published
- 2015
105. Degradation of Beryllium Reflector Properties on the IRT-T Reactor
- Author
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Yuri Chertkov, Mikhail Anikin, Yanina Ermakova, Artem Naymushin, Valeriy Varlachev, and Anastasiya Chyuykina
- Subjects
Isotope ,Nuclear engineering ,Monte Carlo method ,Radiochemistry ,General Engineering ,chemistry.chemical_element ,Reflector (antenna) ,medicine.disease ,Beryllium poisoning ,chemistry ,Neutron flux ,medicine ,Iodine pit ,Beryllium ,Beam (structure) - Abstract
This paper presents the results of a numerical calculation of beryllium poisoning of an IRT-T reactor and its effect on the excess reactivity and neutron flux density in the beam ports. Also, the prediction of 6Li and 3He poison concentrations in the beryllium reflectors of the IRT-T reactor is presented. The results are based on MCU Monte Carlo calculations. The part of reactor history was taken into account to predict reliable values of parasitic isotope concentrations. The impact of shut-down time and operating time on the excess reactivity is shown. The results presented in this paper could be used to perform the safety analysis of an IRT-T reactor.
- Published
- 2015
106. A New Processing Technology of Comprehensive Utilization on the Gold Copper Ore
- Author
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Wen Liang Xiong, Shan Zhi Deng, and Xiao Bo Zeng
- Subjects
Engineering ,chemistry ,business.industry ,Metallurgy ,General Engineering ,chemistry.chemical_element ,Beneficiation ,Technology development ,business ,Tailings ,Copper ore ,Copper ,Copper mine - Abstract
The character of one refractory gold copper mine located in the west of the Sichuan province is so complex, that the valuable element of the ore cannot be recovered by the traditional beneficiation processing. In this paper, a series of tests were conducted to optimize the suitable collector and develop a new beneficiation processing to recover the valuable associated minerals as while as the copper minerals. The results of the tests showed that the bulk-concentrate with 14.73% of Cu grade, 40.59×10-6 of Au grade and 2360.00×10-6 of Ag grade can be obtained from the recommended bulk flotation processing. The recommended processing showed in this paper could greatly improve the copper mineral recovery and reduce emissions of copper tailings, which is very important for the copper beneficiation technology development and the protection of the environment.
- Published
- 2015
107. Analysis and Quantitative Evaluation of Power Grid Corporation’s Carbon Emission Reduction Potential
- Author
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Li Ma, Tao Cai, Xiao Xuan Zhang, and Su Yang
- Subjects
Engineering ,business.industry ,General Engineering ,Environmental engineering ,chemistry.chemical_element ,Grid ,Corporation ,Reduction (complexity) ,chemistry ,Greenhouse gas ,Clean energy ,Power grid ,Line loss ,business ,Carbon - Abstract
As an important part of energy industry, power grid plays a pivotal and irreplaceable role in promoting low-carbon development. In this paper, the carbon emission reduction potential of power grid corporation was systematically analyzed from qualitative and quantitative perspectives respectively. First, this paper discussed the pathways of power grid corporation’s carbon emissions reduction, including decreasing line loss, promoting clean energy development, and so on. Then, a quantitative evaluation model for carbon emissions reduction potential of power grid corporation was developed. Based on the model, the carbon emission reduction benefits that promoted and achieved by State Grid Corporation of China (SGCC) in 2010 and 2015 were calculated. The results show that the carbon emission reduction benefits of SGCC is 138 million tons in 2010, and will be 481.8 million tons in 2015.
- Published
- 2014
108. Effect of Heat Treatment on Conductivity of Cu-1.0Cr-0.12Zr Alloy
- Author
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Yu Chun Zheng, Yong Qiang Qin, Yucheng Wu, Yu Hong, Xin Min Huang, Jie Wu Cui, and Yan Wang
- Subjects
Materials science ,Scanning electron microscope ,Alloy ,Metallurgy ,General Engineering ,chemistry.chemical_element ,engineering.material ,Conductivity ,Microstructure ,Copper ,law.invention ,Brinell scale ,chemistry ,Optical microscope ,law ,engineering ,Solid solution - Abstract
Copper alloys with high strength and high conductivity are a serial of materials with excellent comprehensive performance. However, the strength and the conductivity are a pair of conflicting factors. To resolve this contradiction, Cu-1.0Cr-0.12Zr alloy was studied in this paper. With optical microscope, scanning electron microscope, Brinell hardness and the arms bridge, effects of heat treatment on microstructure and properties of such alloys was studied,and we strived to find a heat treatment processing to achieve the best match between the conductivity and the strength of the alloy. This paper focused on the study of conductive properties of the alloy. The main factor infuencing the conductivity of the alloy was the content of the soluting elements. The higher the content,the lower the conductivity, and vice versa. The results showed that the best comprehensive properties were obtained after solid solution at 920°C and then aging at 450°C for 180 min.
- Published
- 2014
109. A Composite Indicator for Evaluating the Low-Carbon Performance of Cities in Jiangsu Province
- Author
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L.W. Fan and Lu Ping Zhang
- Subjects
chemistry ,Rest (finance) ,General Engineering ,Environmental science ,chemistry.chemical_element ,Average level ,Low-carbon economy ,Composite indicator ,China ,Carbon ,Agricultural economics - Abstract
This paper developed a composite indicator for evaluating the performance of low-carbon economy for the cities in Jiangsu province, China. The empirical results show that the performance of low carbon economy of cities in Jiangsu province may be divided into three levels. The first level include Yangzhou, Zhenjiang, and Nanjing, that the performance is below the province average level; the second level including Huaian, Suqian, Lianyungang, and Nantong which, that the performance is similar with the province average level; the rest of the cities in Jiangsu are set as third level. At same time, this paper analyze some cities’ performance of low carbon economy.
- Published
- 2014
110. Discussion on Determination of Non-Methane Hydrocarbons
- Author
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Zhe Min Li
- Subjects
Measure (data warehouse) ,chemistry.chemical_compound ,chemistry ,Waste management ,General Engineering ,Environmental engineering ,National standard ,Methane - Abstract
This paper summarized the measure methods which include both Chinese national standards and international standards of how to determine the concentration of Non-methane Hydrocarbons (NMHC).Some problems and suggestions were discussed in this paper to improve the level of the measure methods and prompt the establishment of relative Chinese national standard.
- Published
- 2014
111. Research on the Factors of China's Carbon Dioxide Emissions
- Author
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Jun Wei Xu and Xiao Zhi Yang
- Subjects
Index (economics) ,General Engineering ,Environmental engineering ,Divisia index ,Energy consumption ,Decomposition ,Gross domestic product ,chemistry.chemical_compound ,chemistry ,Environmental protection ,Urbanization ,Carbon dioxide ,Environmental science ,China - Abstract
This paper construct the index decomposition model of carbon dioxide and decompose China's current total of carbon dioxide emissions into 11 factors based on the relevant statistical data of 1997-2010 and LMDI. Then, obtain that positive factors such as the economic output, per capita GDP and the level of urbanization play a catalytic role in the growth of carbon dioxide emissions, conversely negative factors such as energy consumption intensity of various departments, the proportion of the rural population and the proportion of the provincial department structure play an inhibitory effect in the growth of carbon dioxide emissions by analysis and calculation; Further, the paper briefly summarizes the results of the above study.
- Published
- 2014
112. Research on the Simultaneous Desulfurization and Denitrification of Fumes by Combining Ozone Oxidation and the Double Alkali Method
- Author
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Bang Fa Peng, Min Xu, Ming Li, Zhao Ji Hu, and Lin Sheng Wei
- Subjects
chemistry.chemical_compound ,Reaction mechanism ,Ozone ,Denitrification ,chemistry ,Inorganic chemistry ,General Engineering ,Partial pressure ,Absorption (electromagnetic radiation) ,Chemical reaction ,NOx ,Flue-gas desulfurization - Abstract
This paper introduced the fundamental principle of the simultaneous desulfurization and denitrification by combining ozone oxidation and the NaOH double alkali method. And the total chemical reaction equations were achieved by analyzing the process of the absorption of the productions of ozone oxidation by NaOH double alkali method. Then, based on thermodynamic principle, the partial pressure of SOx, NOx and CO2 when reactions reached equilibrium were calculated respectively. This paper also studied the reaction mechanism of the absorption of SOx and NOx and analyzed the absorption characteristic of SOx and NOx in absorption solution. The results showed that the simultaneous desulfurization and denitrification by combining ozone oxidation and NaOH double alkali method was feasible. Not only the elimination ratio of SOx and NOx were almost up to 100%, but also CO2 was removed on a considerable scale. The partial pressure of SOx and NOx was very important to the pH value of the absorption solution which affected the elimination ratio of SOx and NOx greatly.
- Published
- 2014
113. An Operating Control Strategy of Zinc Bromine Flow Battery Energy Storage Systems in Microgrid
- Author
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Qiang Li, Yi Bin Tao, Xin Zhen Feng, and Jin Hang Hu
- Subjects
State of charge ,Wind power ,business.industry ,Chemistry ,General Engineering ,Electrical engineering ,Zinc–bromine battery ,Microgrid ,AC power ,business ,Flow battery ,Energy storage ,Renewable energy - Abstract
With the continuous development of distributed solar, wind power and other renewable energy sources, renewable energy sources which has its own features, such as intermittent and randomness volatility, brings great challenges to the stable operation of power grid. Aiming at meeting the requirement of balancing the fluctuating renewable energy sources of micro grid, this paper proposes the operating control strategies of the zinc bromine flow battery storage. Firstly, the equivalent mathematical model based on the working principle of the zinc bromine flow battery is established; Secondly, a dual closed-loop strategy for the DC/DC converter is proposed, of which the inner loop is peak current control on zinc bromine flow battery side inductance while the outer loop is a switch control by constant active power and trickle current. By resorting the DC/AC grid side converter, the stability of DC bus voltage is maintained; Then, this paper proposes the optimization power control strategies of zinc bromine battery energy storage system as a constraint of state of charge and DC bus voltage; Finally, a 50kW zinc bromine flow battery energy storage system test platform is built, and the charging and discharging characteristics of zinc bromine energy storage system (ZESS) is researched in grid-connected mode, the test results have shown that the proposed power optimization control strategies for zinc bromine energy storage system could smooth renewable energy sources power fluctuation.
- Published
- 2014
114. Study on a Sink and Float Test of a Lead-Zinc Ore from Yunnan
- Author
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Sheng Jian and Wen Juan Zhao
- Subjects
geography ,geography.geographical_feature_category ,chemistry ,Metallurgy ,Lead zinc ,General Engineering ,food and beverages ,Environmental science ,chemistry.chemical_element ,Zinc ,Sink (geography) ,Specific gravity - Abstract
The paper analyses problems of a lead-zinc ore from Yunnan with a sink and float test. In the paper, we explored the possibility of pre-discarding about the ore by dense-media process. Dense liquids with the specific gravity of 2.6, 2.7 and 2.8 were used in the test, respectively. -12mm crudes were taken into the test. Finally, it revealed that pre-discarding by dense-media separation can be used in the ore. 2.7 was taken as the best specific gravity of separation. 12~1mm was used as the optimal fraction of pre-discarding by dense-media separation. Pre-discarding rate was 45.53%. The light product with a lead grade of 0.29% and a lead recovery of 4.29% was pre-discarded in which the grade and recovery of zinc were 0.22 and 5.84, respectively.
- Published
- 2014
115. Peculiarity of the Tool-Electrode Wear Mechanism during Surface Machining with Electric Discharges in Pulse
- Author
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Natalia Pînzaru, Dorin Guzgan, Pavel Topală, Vitalie Besliu, and Alexandr Ojegov
- Subjects
Materials science ,Metallurgy ,General Engineering ,Oxide ,chemistry.chemical_element ,Surface finish ,Tungsten ,Pulse (physics) ,chemistry.chemical_compound ,chemistry ,Machining ,Mass transfer ,Electrode ,Composite material ,Layer (electronics) - Abstract
The paper presents the results of experimental research on the wear mechanism of the tool-electrode as a result of machining metal materials by applying electric discharges in pulse. It examines several phenomena noticed on the tool - electrode surface, exactly, the oxide layer formation and the modification of the micro geometry of the tungsten tool electrode surface. The paper presents the experimental results on the behavior of the tool electrode made of stainless steel after the metal parts have been machined. It also presents the phases of mass transfer in the gap between electrodes.
- Published
- 2014
116. The Effects of Natural Pre-Ageing Time on T6 Peak Hardness of R-HPDC 6xxx Series Alloys
- Author
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Gonasagren Govender, Pfarelo Daswa, and Heinrich Möller
- Subjects
Quenching ,business.product_category ,Materials science ,chemistry ,Series (mathematics) ,Ageing ,Aluminium ,Metallurgy ,General Engineering ,chemistry.chemical_element ,Die (manufacturing) ,business ,Copper - Abstract
This paper investigates the influence of natural pre-ageing time on T6 peak hardness of rheo-high pressure die cast (R-HPDC) 6xxx series aluminium alloys. Natural pre-ageing has a negative effect on the 6xxx series Al-Mg-Si alloys that contain higher quantities of Mg2Si (typically > 0.90%). However, a positive effect is observed in alloys with lower quantities of Mg2Si. The negative effect can be attributed to the clustering of solute atoms that form at room temperature because the precipitates which develop directly from clusters formed at room temperature are coarser than those developed in alloys artificially aged immediately after quenching. The opposite occurs in alloys where a positive effect of natural pre-ageing is found. The effects of the duration of natural pre-ageing on the subsequent T6 properties are of importance. In this study the T6 (190oC-4h) hardness values of various R-HPDC 6xxx series alloys were determined after natural pre-ageing times ranging from 0h to 3240 hours. Alloys that show either the positive or the negative effect of natural pre-ageing are used. This paper also compares the influence of natural pre-ageing time on Cu-containing and Cu-free alloys. The addition of copper to the 6xxx series aluminium alloys lessens the negative effect of natural pre-ageing in the higher strength alloys.
- Published
- 2014
117. Nano-Yttrium Aluminium Garnet Interfacial Tension and Viscosity for Enhanced Oil Recovery
- Author
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Keanchuan Lee, Noorhana Yahya, Beh Hoe Guan, and Siti Najwa Che Yaccob
- Subjects
Thermogravimetric analysis ,Materials science ,General Engineering ,chemistry.chemical_element ,Mineralogy ,Yttrium ,chemistry.chemical_compound ,Nanofluid ,chemistry ,Chemical engineering ,Transmission electron microscopy ,Aluminium ,Yttrium aluminium garnet ,Enhanced oil recovery ,Crystallite - Abstract
This paper describes the synthesis of Yttrium Aluminum Garnet (YAG), Y3Al5O12 nanoparticles (NPs) and their application in Enhanced Oil Recovery (EOR). YAG NPs were synthesized by using sol-gel method. These NPs were then synthesized by using Thermal Gravimetric Analysis (TGA), X-Ray Diffraction (XRD) and Transmission Electron Microscope (TEM). The monophasic YAG having crystallites size of 40.98 nm and 40.91 nm were obtained at annealed temperature of 1100 °C and 1200 °C as determined by XRD. Magnetic measurement results show that initial permeability of YAG increased and relative loss factor decreased at high frequency. In this paper, the feasibility of application of YAG nanofluid in EOR was determined by measuring oil-nanofluid interfacial tension and also viscosity of the nanofluid. YAG with 0.5 wt% yielded the lowest IFT. It can be concluded that the synthesized YAG nanoparticle has great potential in EOR applications in the near future.
- Published
- 2014
118. Environmental Factors on Aging of Nitrile Butadiene Rubber (NBR) - A Review
- Author
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Qing Yun Tang and Wei Fang Zhang
- Subjects
Mechanical property ,chemistry.chemical_compound ,Materials science ,Nitrile ,chemistry ,Natural rubber ,Micro analysis ,visual_art ,General Engineering ,visual_art.visual_art_medium ,Composite material - Abstract
Nitrile butadiene rubber (NBR) comes into widespread applications due to the excellent performances, but it is susceptible to aging during its storage and usage periods. This paper surveys the external factors that act on the aging process of NBR. The aging of NBR in liquid environment, and non-liquid environment such as thermo-oxidative aging, ozone aging, stress aging and radiation aging, are considered. The emphasis of present works is test of physical and mechanical properties of NBR, and the micro analysis should gain special attention. One direction of future research on NBR aging is the coupling effects of various factors included in this paper.
- Published
- 2014
119. Carbon Dioxide Transport and Storage
- Author
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Ovidiu Sorin Cupsa and Teodor Popa
- Subjects
Engineering ,Flue gas ,Waste management ,Primary energy ,business.industry ,Fossil fuel ,General Engineering ,Environmental engineering ,Liquefaction ,chemistry.chemical_compound ,chemistry ,Greenhouse gas ,Carbon dioxide ,Enhanced oil recovery ,Carbon-neutral fuel ,business - Abstract
Increased focus on reducing CO2 emissions has created growing interest in CO2 capture from industrial processes for storage in underground formations. New technical solutions, costs and energy requirements for ship-based transport of CO2 are presented. All elements in the transport chain, namely liquefaction, storage, loading system, dedicated CO2 ship (s), onshore loading and unloading, and offshore unloading systems are included in the paper. Over 80 % from the primary energy consumed all over the world is obtained from fossil oil and natural gas. The last researches have shown the energy dependences of these types of fuels. The transition to the economy based on the low influence of the carbon, the carbon capture technology, is the main means to reconsider the fossil fuels for meeting the needs for reduction of negative emissions. This is necessary for keeping the world temperature at normal levels. The main target of this paper is to put highlight the negative effect of CO2 emissions and the interest in recovery of carbon dioxide from flue gases trough multiple factors: the merchant CO2 market, renewed interest in enhanced oil recovery, and the desire to reduce greenhouse gas emissions. It also takes in account modalities of transport and storage of CO2. Solutions for CO2 capture and injection into caverns instead of natural deposits were found worldwide. These solutions are not applicable however all over the world and they are not a priority in the environment protection activity.Another important aspect calls for all merchant ships requirements regarding CO2 emissions through index calculation and development of Management Plan. Also, to increase the control of CO2 it would be useful to identify the caverns where it is possible to deposit the CO2, to build new special ship for CO2 transport or replace natural deposits through CO2 injection.
- Published
- 2014
120. Microwave Differential Thermal Analysis Technique of the Fe2O3+BaCO3 Homogeneous Mixture
- Author
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Sorin Vasile Savu
- Subjects
Materials science ,Infrared ,General Engineering ,Analytical chemistry ,Temperature measurement ,law.invention ,chemistry.chemical_compound ,chemistry ,law ,visual_art ,Differential thermal analysis ,Dielectric heating ,visual_art.visual_art_medium ,Ceramic ,Composite material ,Microwave ,Barium ferrite ,Pyrometer - Abstract
The microwave differential thermal analysis (MW-DTA) is a new procedure to evaluate the materials, barium ferrite type M in this paper, according to the phenomena appeared during the material heating. The paper presents a new evaluation technique which is faster and with low energy consumption. The microwaves are used to heat the material, two infrared pyrometers for monitoring the temperatures on the material surface and a temperature regulator where the data are recorded for evaluation. The material, a homogeneous mixture of Fe2O3+BaCO3, is a ceramic material with good absorbance properties, so the heating will be pure microwave heating. The results and the DTA graphic is automatically generated by the temperature recording device based on the data sensed by the infrared pyrometers. The paper presents technical aspect regarding to the microwave heating and temperature measurement in microwave field and how to make differential thermal analysis in microwave field.
- Published
- 2014
121. Effects of Grain Sizes and Impurities on Thermal Conductivity in Aluminum Nitride
- Author
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Bao Ying Wang, Xue Mei Cai, Jing Mei Wang, and Qian Neng Zhou
- Subjects
Materials science ,Inorganic chemistry ,General Engineering ,chemistry.chemical_element ,Nitride ,Oxygen ,Grain size ,symbols.namesake ,Thermal conductivity ,chemistry ,Aluminium ,Impurity ,visual_art ,visual_art.visual_art_medium ,symbols ,Ceramic ,Composite material ,Debye model - Abstract
The effects of grain sizes and oxygen impurities on thermal conductivity in aluminum nitride (AlN) ceramics has been calculated by density functional perturbation theory (DFPT) and quasi-harmonic approximation (QHA) combined with Debye theory in the paper. From 300K up to 1000K, the predicted thermal properties are compared with experimental data. The agreements with experiment suggest that the theoretical method used in the paper is an effective approach. From our theoretical study, the reduction of thermal conductivity is greater between grain sizes of 1μm and 5μm, while it’s smaller between 8μm and 10μm. Oxygen defects bring about greater influence on thermal conductivity at low temperature than at high temperature. The influence of the oxygen defect is not as significant as the grain sizes when the oxygen concentrations are less than 0.70 at. %, so it’s more important to increase the grain sizes than reduce the oxygen contents in the preparation process to achieve high thermal conductivity AlN ceramics.
- Published
- 2014
122. Effects of Inlet Location on Inert Replacement Efficiency of the Gasoline Vapor in Oil Tank
- Author
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Jian Zhong Zhou, Lin Chuan Wu, Zhou Xu Wei, Jian Ke Ma, Pei Li Zhang, and Xiao Long Lei
- Subjects
Inert ,geography ,Oil tank ,geography.geographical_feature_category ,Waste management ,Petroleum engineering ,Chemistry ,Reid vapor pressure ,General Engineering ,Gasoline ,Inert gas ,Inlet ,Natural gasoline - Abstract
Elimination gasoline vapor in oil tank by mechanical ventilation has disadvantages of long vent time poor safety, and low efficiency, however, those shortcomings can be better conquered if combusted gas is used in the process of the mechanical ventilation. Based on former studies, the research on the effects of inlet location on gasoline vapor’s inert replacement in oil tank by combusted inert gas is studied experimentally in this paper. The conclusions in this paper can provide some useful guidance for the field project of gasoline vapor’s inert replacement in oil tank.
- Published
- 2014
123. A Design of Optical Filter Based on Conjugate Interference
- Author
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Lou Zheng and Zheng Ying Li
- Subjects
Interference filter ,Absorption spectroscopy ,business.industry ,Chemistry ,Electromagnetic spectrum ,General Engineering ,Interference (wave propagation) ,Optics ,Filter (video) ,business ,Optical filter ,Absorption (electromagnetic radiation) ,Astrophysics::Galaxy Astrophysics ,Fabry–Pérot interferometer - Abstract
In this paper, a conjugate interference filter which could be used in gas sensing is presented .The filter consists of two large spot collimators and a gas etalon which has two separate cells:absorption gas chamber and non-absorption gas chamber. When cascading the broadband light to the filter , only light absorbed by the target gas can pass through the filter and the spectrum of output light matches well with the absorption spectrum of target gas.By changing the target gas in the absorption chamber ,filter for various kind of gases can be implemented. In this paper, acetylene is selected as the target gas and the spectrum of light through the filter completely matches the absorption peak of acetylene after parameter adjustments.
- Published
- 2014
124. PZT Piezoelectric Energy Harvester Enhancement Using Slotted Aluminium Beam
- Author
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Hanim Salleh and Mun Heng Lam
- Subjects
Materials science ,business.industry ,Acoustics ,General Engineering ,chemistry.chemical_element ,Structural engineering ,Lead zirconate titanate ,Piezoelectricity ,Renewable energy ,Vibration ,chemistry.chemical_compound ,chemistry ,Aluminium ,Deflection (engineering) ,PMUT ,business ,Voltage - Abstract
This paper presents work on improving piezoelectric energy harvesters. Harvesting energy from vibrations has received massive attention due to it being a renewable energy source that has a wide range of applications. Over the years of development, there is always research to further improve and optimise piezoelectric energy harvesters. For this paper, the piezoelectric specimen is made of PZT (Lead Zirconate Titanate), brass reinforced and has 31.8mm length, 12.7mm width and 0.511mm thick. An external beam is implemented to provide deflection amplification which in turn increases the output of the energy harvester. Depending on the configuration of the external beam, it can amplify output voltage from 100% to 300%.
- Published
- 2014
125. Microstructure Researches of Metallic Composite Foams Based on AlMg Alloys
- Author
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Catalina Nuţescu, Costel Roman, Ioan Carcea, Oana Bălţătescu, and Ioan Rusu
- Subjects
Absorption (acoustics) ,Materials science ,Scanning electron microscope ,Composite number ,General Engineering ,chemistry.chemical_element ,Microstructure ,Metal ,chemistry.chemical_compound ,chemistry ,Aluminium ,visual_art ,Thermal ,visual_art.visual_art_medium ,Silicon carbide ,Composite material - Abstract
Composite materials are the most advanced class of materials invented and produced by humans in modern times as well as a challenge for the future in the field of scientific and technological performance. They are made up of at least two phases of different nature which are so combined to form a new material with a superior combination of properties. They are generally materials with unusual performances on the relationship between properties and specific gravity. Composites are multiphase materials with distinct and well-defined interface between the constituent phases ensuring a transfer of property but can lead to obtaining a product with exceptional performance from the starting material. In this paper we have focused research on Al-Mg alloys with magnesium and silicon carbide (SiC). Stabilized Aluminium Foams (SAF) are new class of materials with low densities and novel physical, mechanical, thermal, electrical and acoustic properties. They offer potential for lightweight structures, for energy absorption, and for thermal management; and some of them, at least, are cheap. Metal foams offer significant performance gains in light, stiff structures, for the efficient absorption of energy, for thermal management and perhaps for acoustic control and other, more specialized, applications. They are recyclable and nontoxic. They hold particular promise for market penetration in applications in which several of these features are exploited simultaneously. The paper presents some results related to the research of metallic foams based on AlMg10 metallic alloy obtained by melt bubbled C4H10 addition of SiC particles. Microsrtucture of these foams is analyzed by using (SEM) Scanning Electron Microscope, laying out the network of pores imbued into each others developed around SiC particles and other issues microstructural characteristics.
- Published
- 2014
126. Application of Biopolymer-Based Adsorbents in Removal of Heavy Metals
- Author
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Jian Can Hu, Wen Li Liu, Min Xiao, and Feng Ming Nie
- Subjects
Materials science ,Chromatography ,General Engineering ,Biosorption ,Chemical modification ,macromolecular substances ,engineering.material ,Chitosan ,chemistry.chemical_compound ,Adsorption ,chemistry ,Chemical engineering ,Chitin ,engineering ,Chelation ,Biopolymer ,Cellulose - Abstract
Heavy metal pollution has raised a lot of concerns because of its bioaccumulation and non-degradability. A variety of methods have been applied in removal of heavy metals. This paper focused on the method of biosorption using biopolymer-based adsorbents in removing heavy metals from waster water. Cellulose and chitin/chitosan are abundant in supply and contain reactive functional groups. Cellulose-based adsorbents prepared from direct chemical modification or graft copolymerization are proved to show chelating ability to bind heavy metals. Chitin-and chitosan-based adsorbents have improved mechanical strength and better resistance to chemical conditions after physical or chemical modification. The regeneration and reusability of biopolymer-based adsorbents were also discussed in this paper.
- Published
- 2014
127. The Partition Period of Thermodynamic Calculation and the Numerical Simulation for Lignite Blended Supercritical Boiler
- Author
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Xu Ao Lu, Cai Ying Ban, Feng Ying Liang, Jian Meng Yang, and Xu Ran
- Subjects
Flue gas ,Mathematical model ,Petroleum engineering ,Computer simulation ,Chemistry ,business.industry ,General Engineering ,Boiler (power generation) ,Boiler furnace ,Supercritical fluid ,Surface heat ,Furnace temperature ,Process engineering ,business - Abstract
The purpose of this paper is to study the impact of furnace temperature and load after blending in lignite, based on CFD software FLUENT-6.3,this paper choose the appropriate geometry model and the physical and mathematical models, and numerical simulation of the different conditions 600MW supercritical once-through boiler blending lignite furnace combustion process is curried out. And through a 600MW supercritical coal-fired boiler furnace lignite blended performed sections thermodynamic calculation under different conditions, worked out the furnace flue gas temperature, CO, CO2concentration distribute trend and radiant heat each section surface heat load conditions. The specific amount were blended with 5%, 10%, 15%, 20% were not dried lignite and dried lignite 20% after five conditions. And obtained a conclusion is the temperature and radiation heating surface flue gas heat load in the overall trend under the various conditions.
- Published
- 2014
128. Effect of Cutting Fluid on Diamond Tool Life under Micro V-Groove Turning of Cobalt-Free Tungsten Carbide
- Author
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Hitoshi Sumiya, Akinori Yui, Katsuko Harano, Takayuki Kitajima, Hajime Ono, and Peter Krajnik
- Subjects
business.product_category ,Materials science ,Metallurgy ,General Engineering ,Diamond ,Edge (geometry) ,engineering.material ,Rake angle ,chemistry.chemical_compound ,chemistry ,Tungsten carbide ,engineering ,Die (manufacturing) ,Cutting fluid ,business ,Groove (music) ,Diamond tool - Abstract
Micro-machining of hard dies and molds for optical parts or precision instruments is required to extend die and mold life. This paper investigates the effect of cutting fluid on diamond tool life under micro V-groove turning of cobalt-free tungsten carbide. Zinc dialkyldithiophosphate fluid (ZnDTP) displayed excellent diamond tool wear resistance in previous experiments. The performance of this cutting fluid is compared to newly developed vegetable oil based cutting fluid with dispersed MoS2 nanotubes. This paper investigates nanopolycrystalline diamond (NPD) tool life with a rake angle of 0° and-30° under continuous micro V-groove turning (i.e. face turning), of cobalt-free tungsten carbide using the developed cutting fluids. Superior diamond tool edge wear resistance is observed when using the dispersed MoS2 nanotubes in vegetable oil and using a NPD tool with a-30° rake angle.
- Published
- 2014
129. Small Hole Drilling for Polyphenylene Sulfide (PPS) - Influence of Depth-of-Cut on Burr Formation
- Author
-
Yongbo Wu, Mitsuyoshi Nomura, Kouta Suzuki, and Masakazu Fujimoto
- Subjects
chemistry.chemical_classification ,Engineering drawing ,Materials science ,Sulfide ,Depth of cut ,business.industry ,General Engineering ,Drilling ,Thrust ,Burr formation ,Semiconductor ,Machining ,chemistry ,Small hole ,Composite material ,business - Abstract
Cutting technology is one of the important methods to fabricate small-sized precision components in the semiconductor, electro-mechanics, and automobile industries. This paper focuses on high efficiency machining of small hole drilling for PPS (Polyphenylene Sulfide). In this paper, drilling experiments were designed to investigate the influence of the depth of cut on the burr formation. The experimental results obtained are as follows, (1) The thrust force and radial force increase with the increase in feed per revolution and depth-of-cut. (2) On the prevention of burr formation, the step feed is better than the non-step feed. Also, the burr formation decreases with the increase in the feed per revolution. (3) The hole straightness increases with the increase in depth-of-cut.
- Published
- 2014
130. Composite Hot Extrusion of Functional Elements
- Author
-
Matthias Haase, Christoph Dahnke, Martin Schwane, A. Erman Tekkaya, and Nooman Ben Khalifa
- Subjects
Materials science ,chemistry ,Aluminium ,Composite number ,Metallurgy ,General Engineering ,Process (computing) ,Embedding ,chemistry.chemical_element ,Extrusion ,Contrast (music) ,Composite material ,Electrical conductor - Abstract
The composite extrusion process, which is investigated at the Institute of Forming Technology and Lightweight Construction (IUL), allows the combination of different materials within an aluminum profile. In contrast to the useage of reinforcing elements, this paper focuses on the embedding of functional elements, such as isolated electric conductors. Results of the experimental and numerical investigations are presented within this paper.
- Published
- 2014
131. Research on Argon Protection when Using WIG Welding
- Author
-
Daniel Ţunea and Mircea Burca
- Subjects
Jet (fluid) ,Argon ,Physics::Instrumentation and Detectors ,Chemistry ,Smoke screen ,Gas tungsten arc welding ,Flow (psychology) ,Nozzle ,General Engineering ,chemistry.chemical_element ,Welding ,Mechanics ,Edge (geometry) ,law.invention ,Physics::Plasma Physics ,law ,Physics::Atomic and Molecular Clusters ,Physics::Chemical Physics ,Composite material - Abstract
The paper presents the theoretical bases of gas flow, as drowned jets, the device used for viewing the pure gas cone (argon) using a smoke screen infused on the edge of the argon jet and then the results of researches carried out on four sizes of nozzles often used in TIG welding. On each type of nozzle the argon flow parameter was varied and the height of the cone of pure argon was photographed and measured. The paper ends with the mathematical correlations that allow us to maximize the height of pure cone argon in relation to its flow. Keywords: TIG welding, Pure argon cone
- Published
- 2014
132. The Increasing of Corrosion Resistance of Low Alloy Carbon Steels Used in Petroleum Industry through Coating with Alloys Based on Fe-Ni-Cr by Thermal Spray
- Author
-
Bogdan Florin Toma, Costica Bejinariu, Stefan Lucian Toma, Margareta Peneoasu, Lucian Eva, and Diana Antonia Gheorghiu
- Subjects
Materials science ,Carbon steel ,Scanning electron microscope ,Alloy ,Metallurgy ,General Engineering ,chemistry.chemical_element ,engineering.material ,Corrosion ,Coating ,chemistry ,engineering ,Thermal spraying ,Layer (electronics) ,Carbon - Abstract
The main objective of this paper is to evaluate the mechanical properties, chemical and corrosion resistance of four types of metallic coatings: FeCr, FeCoCr, and FeCoCrNi, FeCrNi sprayed through thermal spraying in electric arc on an anchor substrate type 95Ni5Al or 78.3Ni20Cr1. 4Si0.3Fe. The five layers tested were deposited on carbon steel support low alloyed and the obtained results have provided a picture regarding the possibilities of using of the deposits. Because these types of alloys are used to increase the wear resistance of tools, it is very important to know their behaviour is saline environment, because the contributions brought by this paper would increase the applicability domain of these materials (could be used to recondition by thermal spraying the tools used in naval and petroleum industry). The researches of the obtained deposits have been carried out through several methods to screen their performance. Therefore, there have been done investigations on the microstructural morphology of the deposit, by optical microscopy (OM) and scanning electron microscopy (SEM). The OM and SEM results have sought to determine the degree of uniformity of the deposits and the amount of pores and oxides in layer. The physical properties of coatings were also evaluated by adhesion and porosity quantification. The corrosion resistance was evaluated by exposing samples in saline fog chamber. The corrosion products formed on the surface layers were investigated by scanning electron microscopy (SEM) analysis of the SEM. The intermediate alloy 78.3Ni20Cr1.4Si0.3Fe used as anchoring layer allowed the reducing of the pores and micro cracks frequently found in the ordinary 95Ni5Al alloy. It has been observed that the deposits based on NiCrCo are good enough to be used as an efficient coating of carbon steel in aggressive marine environments.
- Published
- 2014
133. Effects of Glycerol-Waste Antifreeze Based Grinding Aids on Cement Grinding Characteristics
- Author
-
Yong Su Hwang, Yong Ho Kim, Ju Hyon Yu, Jin Hyok Ri, and Song Gun Kang
- Subjects
Cement ,chemistry.chemical_compound ,Materials science ,chemistry ,Antifreeze ,Metallurgy ,General Engineering ,Glycerol ,Clinker (cement) ,Cement grinding ,Grinding - Abstract
Grinding aids to increase grinding efficiency in cement production are materials that can produce large amounts of high-quality cement in a short time by reducing surface energy by preventing particle agglomeration and improving fluidity. In the paper, a grinding aid using glycerol-waste antifreeze(GAP) is prepared and its effect on the grinding properties of clinker is investigated in contrast to that without the grinding aid. The results are as follows: The angle of repose of the cement powder added with GAP decreases as the grinding time increases (decreases by 3.8° when the grinding time is 60 minutes), indicating that it increases the flowability of the powder. On the contrary, the residual amount of 45µm sieve is also significantly reduced (4.6% decrease) and the specific surface area increases (30.5m2/kg), which results in an increase in the grinding efficiency. In the size range of 3 to 32µm, it increases the particle content, makes the particle size distribution uniform, the 7d and 28d activity index of the powder is improved by 5% and 6%, respectively, and increases the compressive strength of the cement. In addition, it is confirmed that the performance of the TEA grinding aid and the grinding aid are similar, and are very effective in terms of economy.
- Published
- 2021
134. Engineered Nanoparticles for Prevention against CoVID-19 Infection
- Author
-
Raghav Dwivedi, Rajesh Kumar Dwivedi, and Meetkamal
- Subjects
Coronavirus disease 2019 (COVID-19) ,Chemistry ,Drug delivery ,General Engineering ,Nanoparticle ,Nanotechnology ,Engineered nanoparticles - Abstract
The sudden emergence of novel coronavirus CoVID-19 in China during the end of last year and its outburst all around the globe thereafter have raised serious questions about their instant management and diagnostic measures as it is infecting humans around in an exponential manner. The implementation of nanotechnology could perhaps ingenerate the rising distress due to the spread of the disease as the conventional antiviral drugs just control the symptoms. Nanoparticles drug delivery systems are engineered technologies that use nanoparticles for targeted drug delivery and controlled release of therapeutic agents. Nanoparticles based approach can replace the treatment with a more promising one that could meet these challenges. Understanding molecular pathogenesis of CoVID-19 infection is very important to exploit the nanoparticles to fight against it. A lot of nanostructures have been developed with antiviral and antibacterial properties for a variety of drug delivery and biomedical applications. The need of the hour is to exploit nano research to develop effective diagnostics tools, drugs, vaccines to treat and prohibit infection. In this paper an attempt has been made to understand the role and potential of various nanoparticles to inhibit CoVID-19 infection and its toxicity effects.
- Published
- 2021
135. Influence Analysis of the Controllable Factors on the Objective Functions for Optimizing the Welding of PE 100 Pipelines for Natural Gas Distribution
- Author
-
Marius Cocard
- Subjects
chemistry.chemical_classification ,Materials science ,Thermoplastic ,Petroleum engineering ,Distribution (number theory) ,business.industry ,05 social sciences ,General Engineering ,02 engineering and technology ,Welding ,021001 nanoscience & nanotechnology ,law.invention ,Pipeline transport ,chemistry ,law ,Natural gas ,0502 economics and business ,Influence analysis ,0210 nano-technology ,business ,050203 business & management - Abstract
The paper presents a series of experimental researches performed using the design of experiments method RSD (Response Surface Design) for modeling and optimizing the welding process of PE 100 pipelines, used in natural gas distribution. In this sense, the aim was to analyze the influence of controllable factors such as pressure, temperature and time on the objective functions, aiming to obtain certain characteristics of the welded joint. By modeling the welding process, based on the results obtained, an optimal welding procedure was established and validated to meet the conditions imposed on the objective functions.
- Published
- 2021
136. Performance Comparison of Microchannel Heat Sink Using Boron-Based Ceramic Materials
- Author
-
Tanbir Sarowar
- Subjects
Microchannel heat sink ,Materials science ,020209 energy ,General Engineering ,chemistry.chemical_element ,02 engineering and technology ,engineering.material ,021001 nanoscience & nanotechnology ,Ultra-high-temperature ceramics ,chemistry ,Performance comparison ,0202 electrical engineering, electronic engineering, information engineering ,engineering ,Composite material ,0210 nano-technology ,Boron - Abstract
Microchannel heat sink plays a vital role in removing a considerable amount of heat flux from a small surface area from different electronic devices. In recent times, the rapid development of electronic devices requires the improvement of these heat sinks to a greater extent. In this aspect, the selection of appropriate substrate materials of the heat sinks is of vital importance. In this paper, three boron-based ultra-high temperature ceramic materials (ZrB2, TiB2, and HfB2) are compared as a substrate material for the microchannel heat sink using a numerical approach. The fluid flow and heat transfer are analyzed using the finite volume method. The results showed that the maximum temperature of the heat source didn’t exceed 355K at 3.6MWm-2 for any material. The results also indicated HfB2 and TiB2 to be more useful as a substrate material than ZrB2. By applying 3.6 MWm-2 heat flux at the source, the maximum obtained surface heat transfer coefficient was 175.2 KWm-2K-1 in a heat sink having substrate material HfB2.
- Published
- 2021
137. Tungsten Inert Gas (TIG) Cladding of TiC-Fe Metal Matrix Composite Coating on AISI 1020 Steel Substrate
- Author
-
Waquar Alam, Sujeet Kumar, Mayank Kumar Chaubey, and Anil Kumar Das
- Subjects
Cladding (metalworking) ,Materials science ,Gas tungsten arc welding ,Metallurgy ,Metal matrix composite ,General Engineering ,chemistry.chemical_element ,02 engineering and technology ,Tungsten ,engineering.material ,021001 nanoscience & nanotechnology ,Microstructure ,Indentation hardness ,020303 mechanical engineering & transports ,0203 mechanical engineering ,chemistry ,Coating ,engineering ,0210 nano-technology ,Inert gas - Abstract
TiC – Fe composite coating was produced on AISI 1020 steel by the tungsten inert gas (TIG) cladding process to increase the hardness and wear resistance properties of the substrate. In this paper authors have investigated the effect of process parameters on the microstructure and hardness value of the coated layer. In this TIG cladding process the variable parameter is only current, whereas the other parameters such as scanning speed, standoff distance, and voltage and gas flow rate are fixed. Fe and TiC powders were mixed in the proper ratio of 80wt% - 20wt% and 90wt% - 10wt% respectively. The microstructure and micro-hardness value of the samples were investigated by the scanning electron microscope (SEM) and Vickers micro hardness tester. The result of SEM shows the distribution of the coating powder in the cladded zone. Micro hardness profile shows the variation of the hardness value in the cladded zone as well as in the substrate. The hardness value decreases with increase in distance from top surface of the cladded layer, which is due to difference in cooling rate. Also, the hardness value of cladded layer decreases with increase in current from 140A to 150A. The maximum hardness value of cladded layer was achieved as 262 HV0.05with 140A current and composition of 90 wt.% - 10wt% (Fe - TiC), which was nearly two times higher than that of the as received AISI 1020 steel substrate. Keywords TIG, Microstructure, Micro hardness, Titanium Carbide (TiC), Iron (Fe) powder.
- Published
- 2020
138. Temperature Effect on the Modal Frequencies of Aluminum Honeycomb Plate
- Author
-
R. Amri
- Subjects
Materials science ,General Engineering ,chemistry.chemical_element ,Natural frequency ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Finite element method ,020303 mechanical engineering & transports ,Modal ,0203 mechanical engineering ,chemistry ,Aluminium ,Aluminum honeycomb ,Composite material ,0210 nano-technology - Abstract
The aim of this paper is to perform a study on how the elevated temperature and gradient of temperature affect the natural frequencies of aluminum honeycomb plate. This study is carried out for temperature range between 200K and 800K, and gradient temperature (ΔT) across the thickness direction of the plate between [0-500K]. Different honeycomb plate geometries have been selected for the analysis, by changing the core thickness, skins thickness and cell size. The obtained results show that the effect of the temperature is noticeable. At temperature 800K, the natural frequencies decrease by 16.1% in comparison to their values at ambient temperature (300K). That means, high temperature makes the material suffers from weak rigidity, which furthermore contribute to high decrease of all the frequencies. In addition, investigations carried out in this work relate to the modal analysis of the honeycomb plate, under various gradients of temperature across the core of the plate. The obtained results show that the gradient of temperature has an effect on the modes of vibration of the honeycomb plate. This effect becomes significant when the gradient of temperature is very high. At ΔT equal 500K, the natural vibration modes decrease by 9.5% in comparison to the case where no gradient of temperature (ΔT = 0K) is applied between the two faces of the plate. Keywords: honeycomb panel; aluminum; natural frequency; finite element method; temperature.
- Published
- 2020
139. Study on Deformation-Induced Pearlite Transformation in Vanadium Microalloyed Eutectoid Steel
- Author
-
Xin Ping Mao, Gang Zhao, Si Qian Bao, and Cai Zhen
- Subjects
010302 applied physics ,Materials science ,Precipitation (chemistry) ,Metallurgy ,technology, industry, and agriculture ,0211 other engineering and technologies ,General Engineering ,Vanadium ,chemistry.chemical_element ,02 engineering and technology ,Deformation (meteorology) ,01 natural sciences ,chemistry ,0103 physical sciences ,Pearlite ,021102 mining & metallurgy ,Eutectic system - Abstract
In this paper, the hot compression tests were performed to study on deformation-induced pearlite transformation in vanadium microalloyed eutectoid steel. The results showed that volume fraction of deformation -induced pearlite were higher and the pearlite were spheroidized better under lower strain rate and higher strain in vanadium microalloyed steel. Ferrite grains and granular cementites were further refined through vanadium microalloying combined with deformation-induced pearlite transformation .Vanadium dissolved in γmatrix could retard deformation-induced pearlite transformation under low strain, vanadium carbides precipitated due to strain-induced precipitation eliminate the retardation when the strain was increased to a certain extent. Under heavy deformation, ferrite grains and granular cementites in vanadium microalloyed steel were finer compared with vanadium free steel.
- Published
- 2019
140. Performance of Rice Husk Ash - Calcium Carbide Waste in Concrete
- Author
-
Jimoh Abdullahi Alao, Wasiu John, and Lawrence Zahemen Tuleun
- Subjects
Materials science ,Calcium carbide ,05 social sciences ,Metallurgy ,General Engineering ,050109 social psychology ,Pozzolan ,Husk ,chemistry.chemical_compound ,Compressive strength ,Flexural strength ,chemistry ,0502 economics and business ,Setting time ,0501 psychology and cognitive sciences ,050203 business & management - Abstract
This paper examines and present the findings of the physical and mechanical properties of concrete containing rice husk ash (RHA), and the blend of rice husk ash with calcium carbide waste (RHA-CCW). Concrete cubes, cylindrical and beam specimens containing different percentages of RHA and RHA-CCW by weight of cement (5, 10, 15 and 20 %) were cast. Compressive strength test was carried out after the specimens were cured in water for 7, 14, 28 and 56 days. Test for tensile and flexural strength was carried out after 28 days curing. Initial and final setting time test was carried out on mortar specimens with the same percentage of RHA and RHA-CCW. Bogues model was used to determine the elemental and compound composition of cement when blended with the RHA and RHA-CCW. From the results obtained, the compressive strength of RHA-CCW concrete increases as cement is partially replaced with RHA-CCW content, with the maximum strength attained at 5 % replacement. RHA concrete attains it maximum strength at 10 % replacement. The maximum compressive strength results obtained for both RHA and RHA-CCW concrete were higher than the strength of plain concrete (0 % replacement) by 1.1 % and 14.7 % respectively. Interestingly, results obtained for the tensile strength also shows a similar pattern of strength development with that of compressive strength. The flexural strength properties of concrete was improved upon when RHA-CCW was used in concrete compared to RHA. The results of setting time test for RHA mortar showed a decrease in setting time, while the reverse was the case for RHA-CCW mortar. In conclusion, provided adequate curing is maintained, the used of RHA-CCW gives a better performance in concrete than RHA. However, they both perform better in concrete than the plain, and can be used as additives in concrete production.
- Published
- 2019
141. Surface Properties of Magnesium-Aluminium Hydrotalcite-Like Compound Characterized by Inverse Gas Chromatography
- Author
-
Cheng Qian, Xing Wen Zheng, Jin Long Fan, Liang Qin Zhou, and Yuan Dong
- Subjects
Materials science ,Hydrotalcite ,Magnesium ,Enthalpy ,Inorganic chemistry ,General Engineering ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,chemistry ,Aluminium ,Inverse gas chromatography ,0210 nano-technology - Abstract
In this paper, the Mg-Al hydrotalcite-like compound (Mg-Al-HTLC) was synthesized by hydrothermal method at 373K. Structure and morphology of Mg-Al-HTLC was obtained with X-ray diffraction (XRD), scanning electron microscope (SEM) and Fourier transform infra-red spectroscopy(FTIR). A series of polar and non-polar molecules were used for probes, surface properties of Mg-Al-HTLC was studied by inverse gas chromatography (IGC) at 353K, 363K, 373K, 383K respectively. The retention volume was utilized for evaluating the free energy of adsorption (-ΔGSP), the dispersive component of the surface energy(γsD), as well as the enthalpy and entropic component(ΔHSP, -ΔSSP). XRD results reveal that the Mg-Al-HTLC has high crystallinity and perfect layered structure. The results of IGC show that Mg-Al-HTLC would adsorb straight-chain alkanes spontaneously, and the values of γsDwere similar at all temperature. It reveals Mg-Al-HTLC is a material with particular characteristics of both acid and base. This study illustrates that, as a method to evaluate the surface properties of material , IGC method is dependable and significant.
- Published
- 2019
142. Evaluation of Coefficient of Thermal Expansion of Zirconium by Using Dilatometer & Ansys
- Author
-
D. Tarun, M. Kamal Tej, B.V.S. Raghu Vamsi, Repalle Jithendra Kumar, and T. Siva Krishna
- Subjects
Zirconium ,Materials science ,General Engineering ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Thermal expansion ,010309 optics ,chemistry ,0103 physical sciences ,Dilatometer ,Composite material ,0210 nano-technology - Abstract
Zirconium alloys are solid solutions of zirconium or other metals. Zirconium has very low absorption cross-section of thermal neutrons. Zirconium has high corrosion resistance, ductility and hardness. Zirconium is mainly used as a good refractory metal. Zirconium can be manufactured by using standard fabrication techniques. In the present scenario zirconium alloys are used in water reactors for the cladding of fuel rods in nuclear reactors in nuclear technology. We use the composition of zirconium alloys as more than 94.5 weight percentage of zirconium and less than 2.45 weight percentage of copper which are added to improve mechanical, thermal properties and corrosion resistance. This paper first focuses on the study of thermal properties of Zirconium. And this particularly concentrated on variation of Coefficient of Thermal Expansion by varying temperatures by using Dilatometer and as well as ANSYS
- Published
- 2018
143. Mathematical Modelling of Material Flow during Friction Stir Welding of Aluminium Alloys
- Author
-
Cristian Ciucă, Cosmin Ighisan, and Bogdan Radu
- Subjects
0209 industrial biotechnology ,Thesaurus (information retrieval) ,Materials science ,020502 materials ,Metallurgy ,General Engineering ,chemistry.chemical_element ,02 engineering and technology ,Material flow ,020901 industrial engineering & automation ,0205 materials engineering ,chemistry ,Aluminium ,Friction stir welding - Abstract
The paper presents the results of a mathematical model of the material flow during Friction Stir Welding (FSW) of aluminium alloys using a Finite Element Analysis. The authors presented their work on a two-dimensional visco-plastic model, using User Define Functions (UDF) in a commercial CFD code (FLUENT). The model developed was validated by microstructural investigations on experimental FSW joints and by a comparative analysis of temperature distribution field of the experimental FSW joint and numerical simulated model. The results confirmed that the mathematical model describes with a good precision the material flow and temperature field during FSW process.
- Published
- 2018
144. Establishing the Dependence of Output Parameters Depending on Local Process Conditions for Friction Stir Welding of Pure Copper Plates
- Author
-
Lia Nicoleta Boţilă, Eduard Niţu, Ana Boşneag, and M A Constantin
- Subjects
010302 applied physics ,Imagination ,Thesaurus (information retrieval) ,Materials science ,Chemical substance ,media_common.quotation_subject ,Metallurgy ,General Engineering ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Microstructure ,01 natural sciences ,Copper ,Search engine ,chemistry ,0103 physical sciences ,Ultimate tensile strength ,Friction stir welding ,0210 nano-technology ,media_common - Abstract
Welding copper and its alloys is usually difficult to achieve by conventional fusion welding processes because of high thermal diffusivity of the copper, which is at least 10 times higher than most steel alloys, in addition to this, there are the well-known disadvantages of conventional fusion welding represented by necessity of using alloying elements, a shielding gas and a clean surface. To overcome these inconveniences, Friction Stir Welding (FSW), a solid state joining process that relies on frictional heating and plastic deformation, is being explored as a feasible welding process. In order to achieve an increased welding speed and a reduction in tool wear, this process is assisted by another one (TIG) which generates and adds heat to the process. The research includes two experiments for the FSW process and one experiment for tungsten inert gas assisted FSW process. The process parameters that varied were the rotational speed of the tool [rpm] and the welding speed [mm/min] while the compressive force remained constant. The purpose of this paper is to correlate the evolution of temperature, tensile strength, elongation and microscopic aspect with the linear position on the joint (local process parameters) for each experimental case and then make comparisons between them, and to identify and present the set of process parameters that has the best mechanical properties for this material.
- Published
- 2018
145. Microstructural Characterization of the Friction Stir Welding (FSW) Joints from Dissimilar Metallic Aluminium - Copper Alloys
- Author
-
Lia Nicoleta Boţilă, Bogdan Radu, Cristian Ciucă, Radu Cojocaru, and Iosif Hulka
- Subjects
Metal ,Materials science ,chemistry ,Aluminium ,visual_art ,Metallurgy ,General Engineering ,visual_art.visual_art_medium ,chemistry.chemical_element ,Friction stir welding ,Microstructure ,Copper ,Characterization (materials science) - Abstract
During Friction Stir Welding (FSW) process materials to be joined will be subject of intense mechanical and thermal processes, characteristic to this solid state welding process. As a result, the welded materials will suffer quick heating and cooling cycles that will be overlapping on large plastic deformation/flow of the materials, which will produce their phase and structural transformation as well as modification of their properties. The paper investigates the structural transformation of the materials and will analyse the influence between the FSW process and these transformations.
- Published
- 2018
146. Analysis and Correlation of Output Parameters against Input Parameters for Friction Stir Welding of Three Dissimilar Aluminum Alloy
- Author
-
Cristian Ciucă, Ana Boşneag, Eduard Niţu, and M A Constantin
- Subjects
Materials science ,020502 materials ,Alloy ,General Engineering ,chemistry.chemical_element ,02 engineering and technology ,engineering.material ,021001 nanoscience & nanotechnology ,Microstructure ,Indentation hardness ,0205 materials engineering ,chemistry ,Aluminium ,engineering ,Friction stir welding ,Composite material ,0210 nano-technology - Abstract
Friction Stir Welding, abbreviated FSW is an innovative joining process. The FSW is a solid-state welding process with a lot of advantages comparing to the traditional arc welding, such as the following: it uses a non-consumable tool, it results of good mechanical properties, it can use dissimilar materials and it have a low environmental impact. First of all, the FSW process was developed to join similar aluminum plates, and now, the technology was developed and the FSW process is used to weld large types of materials, similar or dissimilar. In this paper it is presented an experimental study and the results of it, which includes the welding of three dissimilar aluminum alloy, with different chemical and mechanical properties. This three materials are: AA2024, AA6061 and AA7075. The welding joints and the welding process were analyzed considering: process temperature, micro-hardness, macrostructure and microstructure.
- Published
- 2018
147. Experimental Study on the Strength and Damping Properties of Polymer Recycled Concrete
- Author
-
Feng Zhang, Jian Xin Zhou, Wei Liu, and Guo Tai Li
- Subjects
chemistry.chemical_classification ,Damping ratio ,Materials science ,Compressive strength ,chemistry ,021105 building & construction ,0211 other engineering and technologies ,General Engineering ,020101 civil engineering ,02 engineering and technology ,Polymer ,Composite material ,0201 civil engineering - Abstract
This paper designed and completed the different polymer dosage of recycled concrete, was prepared by adding amount was 7%, 14%, 21%, 14% styrene butadiene latex recycled concrete, recycled rubber powder recycled concrete and ordinary concrete block, the cube compressive strength and damping performance test. The cube compressive strength of concrete test according to the ordinary concrete mechanics performance test methods, specimen is 150×150×150 mm cube specimens, pressure testing machine loading speed is 0.5 MPa per second. The concrete damping performance test is carried out according to the free attenuation method, with the hammer vibration test device, the test piece is T type. Based on the damage form of specimens, the compressive strength and damping performance analysis, and compared with ordinary concrete as the benchmark analysis test results show that the polymer recycled concrete cube compressive strength failure process and failure pattern basic consistent with common concrete. In the water/cement ratio, sand ratio, and amount of material per unit volume is the same, under the condition of polymer recycled concrete cube compressive strength is lower than normal concrete, damping performance is higher than that of ordinary concrete, the compressive strength is inversely proportional to the damping sexual relations.
- Published
- 2018
148. Influence of the Iron Oxide Phases in Steam Oxidation on the Mechanical Properties and Abrasive Wear of Sintered Iron Materials
- Author
-
Octavian Potecaşu, Florin Bogdan Marin, Mihaela Marin, and Florentina Potecaşu
- Subjects
010302 applied physics ,Materials science ,Abrasive ,Metallurgy ,technology, industry, and agriculture ,General Engineering ,Iron oxide ,food and beverages ,Sintering ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Microstructure ,01 natural sciences ,law.invention ,Stress (mechanics) ,chemistry.chemical_compound ,chemistry ,Optical microscope ,law ,Powder metallurgy ,Phase (matter) ,0103 physical sciences ,0210 nano-technology - Abstract
The objective of this research work was to study the influence of the iron oxide phase resulted during steam oxidation of the sintered steels specimens obtained by powder metallurgy (P/M) route. Steam oxidation is a surface treatment applied to sintered iron parts, as an economic way to reduce the interconnected pores. In powder metallurgy products, the networks of pores are specific, who can be stress concentraions and can produce cracks in material. By steam oxidation treatment the interconnected porosity is closed by sealing them with iron oxides phases. Also, other properties of sintered PM steels are improved. The specimens analyzed in this paper were produced from atomised iron powders, compacted at room temperature at pressures of 600 MPa, sintered for 120 minutes at 1150o C in a laboratory furnace and then subjected to a continuous steam oxidation at 550o C for 60 minutes. Investigations on the structural, mechanical and abrasive wear properties were performed. The microstructure and the pore morphology of the sintered and steam oxidation samples were studied on using optical microscope.
- Published
- 2017
149. Properties of Alkali Activated Ground Granulated Blast Furnace Slag Based Geopolymers
- Author
-
Ilenuta Severin and Maria Vlad
- Subjects
Materials science ,Metallurgy ,0211 other engineering and technologies ,General Engineering ,Sodium silicate ,02 engineering and technology ,Straw ,021001 nanoscience & nanotechnology ,Red mud ,Geopolymer ,chemistry.chemical_compound ,Compressive strength ,chemistry ,Ground granulated blast-furnace slag ,Sodium hydroxide ,021105 building & construction ,Composite material ,0210 nano-technology ,Porosity - Abstract
Ground granulated blast furnace slag, red mud, wheat straw ash are secondary material which after alkaline activation can be used in the construction materials’ domain. Their disposal poses a threat to the environment, whereas by reusing them we would be able to reduce this negative impact. This paper describes the research carried out in order to synthesise some geopolymer recipes, which are based on ground granulated blast furnace slag, red mud and wheat straw ash, alkaline activated with sodium hydroxide or a solution made with sodium hydroxide and sodium silicate. Factors that influence the compression strength have been studied such as: the nature of the alkaline activator, the chemical composition of solid materials in the recipes and the curing time. The geopolymer samples have been dried at room temperature for 7 and 28 days, respectively, and after the compressive strength tests has been made. Following this research it has been found out that NaOH/Na2SiO3 activated geopolymer samples have shown a higher resistance in the compressive strength. From the SEM analysis it has been found out that the samples with a higher amount of ground granulated blast furnace slag in their composition had a more homogeneous and less porous design than those with a smaller amount of ground granulated blast furnace slag.
- Published
- 2017
150. Influence of Different Galvanic Sludge Types on the Extraction Efficiency of Chromium Ions
- Author
-
Maria Vlad, Maria Iuliana Mărcuș, and A. Mihaela Mîţiu
- Subjects
Cadmium ,Materials science ,Waste management ,Extraction (chemistry) ,General Engineering ,chemistry.chemical_element ,02 engineering and technology ,010501 environmental sciences ,021001 nanoscience & nanotechnology ,01 natural sciences ,Chromium ,Wastewater ,chemistry ,Hazardous waste ,Plating ,Sewage treatment ,0210 nano-technology ,Sludge ,0105 earth and related environmental sciences - Abstract
Galvanic sludge resulting from wastewater treatment is a hazardous waste that can be removed by disposal only after neutralization process. A chemically complex sludge is a mixture of hydroxides of the many heavy metals such us: copper, iron, nickel, chromium, cadmium and zinc. There is worldwide, a concern to develop methods and techniques for extraction and recovery of the metal compounds from sludge out of treatment processes of wastewater from metal plating works (washing wastewater and technological solutions) in order to reinsert them into existing industrial flows or to capitalize them in other industries, leading to a significant reduction of environmental pollution.This paper presents the results of the scientific activity in the laboratory with a view to recover Cr (VI, III) from two types of galvanic sludge: a fresh sludge from wastewaters treatment by Lancy technique and an old sludge, stabilized by disposal for many years. Chromium extraction was performed by alkaline sludge oxidation to obtain salts of chromium. The extraction efficiency was 84.20 % from fresh sludge (in one stage) and 93.19% from old sludge (in two stages).
- Published
- 2017
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