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Global warming has been documented as one of the world’s foremost ecological concerns. Although it is difficult to totally end human related global warming, there is a possibility to alleviate these effects through a wide spectrum of options. One such possibility is the reduction of atmospheric carbon dioxide emissions, a major greenhouse gas widely thought to be responsible for global warming. This paper therefore looks at an experimental validation of gas separation by means of a high selective membrane for CO2 recovery applications. Analysis of the results obtained is in good agreement with literature experimental data. Additional results show that CO2 selectivity factor is reasonable for capture of CO2 from N2 as a key constituent in a flue gas stream.

The Importance of this Paper is Determined by the Research of Conditions of Photosorption Processes Occurance on the Surface of Aerosol Particles Resulting in the Removal of Toxic Substances from the Atmosphere. Acid-Base Properties of Oxygen-Containing Calcium Compounds being Components of Troposphere Aerosol Particles were Studied by Methods of Ph-Metry and Hammet’s Indicators. the Basic Properties of the Investigated Compounds Surfaces are Predominant Ones: рНiis of Calcium Oxide and Hydroxide has a Value of 9.3 – 9.5, and that for Carbonate and Calcite Equals to 12.3-12.4. Indicator Method Distinguishes Three Areas of Spectrum Corresponding to Lewis Base, and Brensted Neutral and Basic Centers. the Intencity of Peaks is much Higher for Ca(OH)2 and CaO. the Interaction Process of Halogen-Containing Organic Compounds (Freons: 134a, 22 and 12) with Calcium Carbonate Surface under Illumination in Conditions close to Tropospheric Conditions was Studied. it is Shown that the Interaction is the Destructive Photosorption of Freons (134a or 22). the Spectral Dependence of Effective Quantum Yield of Destructive Photosorption is Determined. as a Result of the Interaction Calcium Fluoride and Calcium Chloride are Formed at the Surface.

The design of layers for multilayer flame-resistant glass is a vital task in terms of upgrading fire resistance of window glass units. This paper describes chemical modification of flame-proof acrylate hydrogel layers and shows experimentally how a cross-linking agent — hexamethoxymethylmelamine ether – influences the kinetics of hydrogel polymerization and the enhancement of carbonated structures yield. It has been determined that adding HMMM to the hydrogel composition raises the coke residue yield from 10 % to 35 % and increases the 19 mm thick glass flame resistance class from EI30 to EI50.

The paper is dedicated to the research of calcium-phosphate coatings formed on the surface of the polymer layers (copolymer tetrafluoroethylene with vinylidene fluoride) by pulsed laser deposition. The calcium-phosphate coatings were formed using two different by composition targets. The morphology of the obtained coatings was analyzed by Scanning Electron Microscopy, the elemental composition was analyzed by Energy Dispersive Analysis, and the chemical composition was analyzed by Fourier Transform Infrared Spectroscopy.

Since squeeze casting process is considered as a new technology for light alloys like aluminum and magnesium, more basic research is required for a scientific understanding of the practice. In distinct, as a cost-effective and resource-efficient tool, advanced numerical modelling in conjunction with dynamic boundary conditions and capabilities of predicting the formation of casting defects have to be fully developed for the optimization of squeeze casting processes. In squeeze casting, an external pressure is applied to molten metal before, during and after its solidification, which makes the condition at the casting die interface different from other typical casting techniques. In this paper, Finite Difference Method (FDM) is used to investigate the effect of heat transfer during squeeze casting process and the relationship between casting temperature and solidification on Al-Si alloys.

An important step of a new process being developed for the beneficiation of the mineral zircon (Zr (Hf)SiO4) to produce nuclear grade zirconium (Zr) metal, is the separation of the Zr from the hafnium (Hf). Zr ores typically contain between 1 and 3% Hf , whereas the use of Zr metal in the nuclear industry requires a Hf content 2•SiO2) with ammonium bifluoride (ABF). The separation involves the selective sublimation of the two tetrafluorides in an inert atmosphere under controlled conditions, and subsequent similarly selective desublimation. An accurate estimation of the sublimation rates the zirconium tetrafluoride (ZrF4) and hafnium tetrafluoride (HfF4) as a function of temperature is required since this forms the basis of the development of a sublimation model to determine whether the concept under consideration is theoretically possible. The sublimation kinetics of ZrF4is reported in this paper.

Lasers have the potential for the micromachining of germanium (Ge). However, the thermal damages associated with the laser machining process need to be properly controlled. To minimize the thermal damages, a hybrid laser-waterjet ablation technology has recently been developed for micromachining. This paper presents an experimental study to assess the machining performances in microgrooving of Ge by using a nanosecond laser and the hybrid laser-waterjet technology. The effects of laser pulse energy, pulse overlap and focal plane position on the groove geometry and heat affected zone (HAZ) size are analyzed and discussed. It is shown that the hybrid laser-waterjet technology can give rise to narrow and deep microgrooves with minimum HAZ.

Delivery of polymer melts into the mold cavity is the most important stage of the injection molding process. This paper shows the influence of cavity surface roughness and technological parameters on the flow length of rubber into mold cavity. The fluidity of polymers is affected by many parameters (mold design, melt temperature, injection rate and pressures) and by the flow properties of polymers. Results of the experiments carried out with selected types of rubber compounds proved a minimal influence of surface roughness of the runners on the polymer melt flow. This considers excluding (if the conditions allow it) the very complex and expensive finishing operations from the technological process as the influence of the surface roughness on the flow characteristics does not seem to play as important role as was previously thought. Application of the measurement results may have significant influence on the production of shaping parts of the injection molds especially in changing the so far used processes and substituting them by less costly production processes which might increase the competitiveness of the tool producers and shorten the time between product plan and its implementation.

Little research was done to investigate possible utilization of irradiated materials after the end of their lifetime. This research paper deals with the possible utilization of irradiated high-density polyethylene (HDPEx) after its service life. Irradiated HDPE was used as filler into the virgin low-density polyethylene (LDPE). Three material combinations were investigated (powder/powder, granules/powder and granules/grit) and influence of the filler on optical behavior was measured. Terahertz spectroscopy at wide range of frequencies was used for refractive index determination. According to measured data there is significant influence by the amount of the filler. Moreover influence of particle size was also observed. All three combinations have similar curve courses; however the most consistent results were achieved at the powder/powder combination. Behavior of virgin LDPE and virgin HDPE is in correlation with previous findings.