1. Catalytic oxidation of pulping effluent by activated carbon-supported heterogeneous catalysts
- Author
-
Anurag Garg and Bholu Ram Yadav
- Subjects
Biochemical oxygen demand ,02 engineering and technology ,010501 environmental sciences ,Wastewater ,01 natural sciences ,Oxygen ,Waste Disposal, Fluid ,Lignin ,Wet Air Oxidation ,Waste Management and Disposal ,Water Science and Technology ,Chemistry ,Chemical oxygen demand ,General Medicine ,Cerium ,021001 nanoscience & nanotechnology ,Pulping Effluent ,0210 nano-technology ,Oxidation-Reduction ,medicine.drug ,Paper ,Inorganic chemistry ,Compound ,chemistry.chemical_element ,Industrial Waste ,Catalyst Characterization ,Catalysis ,Water Purification ,Oxide Catalysts ,Paper-Mill Effluent ,Metal Leaching ,medicine ,Environmental Chemistry ,Wet oxidation ,Effluent ,Catalytic Wet Oxidation ,0105 earth and related environmental sciences ,Biological Oxygen Demand Analysis ,Manganese ,Phenol ,Heterogeneous Catalysts ,Liquor ,Carbon ,Catalytic oxidation ,Ferulic Acid ,Removal ,Water Pollutants, Chemical ,Copper ,Activated carbon - Abstract
The present study deals with the non-catalytic and catalytic wet oxidation (CWO) for the removal of persistent organic compounds from the pulping effluent. Two activated carbon-supported heterogeneous catalysts (Cu/Ce/AC and Cu/Mn/AC) were used for CWO after characterization by the following techniques: temperature-programmed reduction, Fourier transform infrared spectroscopy and thermo-gravimetric analysis. The oxidation reaction was performed in a batch high-pressure reactor (capacity = 0.7 L) at moderate oxidation conditions (temperature = 190°C and oxygen pressure = 0.9 MPa). With Cu/Ce/AC catalyst, the maximum chemical oxygen demand (COD), total organic carbon (TOC) and lignin removals of 79%, 77% and 88% were achieved compared to only 50% removal during the non-catalytic process. The 5-day biochemical oxygen demand (BOD5) to COD ratio (a measure for biodegradability) of the pulping effluent was improved to 0.52 from an initial value of 0.16. The mass balance calculations for solid recovered after CWO reaction showed 8% and 10% deduction in catalyst mass primarily attributed to the loss of carbon and metal leaching. After the CWO process, carbon deposition was also observed on the recovered catalyst which was responsible for around 3–4% TOC reduction.
- Published
- 2016