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Dissolved organic carbon (DOC) is an essential component of the biogeochemical marine system, effecting biological and chemical reactions that take place in the sea. DOC represents a dynamic component of the global carbon cycle. This paper reports 25 years of measurements of DOC content and distribution at seven stations along the transect Po River delta – Rovinj in the northern Adriatic (NA). The results show strong temporal and spatial variability: (1) The highest average DOC concentrations were observed in 1998 and 2002 (143 μmol/L and 137 μmol/L, respectively); (2) The minimum average DOC was recorded in 2006 (88 μmol/L) and (3) The short-term DOC accumulation (up to 203, average 102 μmol/L) for the years 2009 to 2012, was observed during the summer and autumn months followed by unusually low DOC concentrations during the winter and spring. The DOC results from the more recent monitoring at the same stations indicate primarily oligotrophic characteristics of the NA seawater (88 μmol/L). The results of DOC variability and distribution in the NA appears to be strongly influenced by complex circulation patterns. This paper provides a “link” between the Ionian circulation and the NA ecosystem as a part of the recently identified Adriatic-Ionian Bimodal Oscillating System (BiOS). A good agreement between the BiOS oscillation and other variables related to the DOC concentration, like the NA A and B winter types, the Po River discharge, salinity, chlorophyll a , occurrence of hypoxic-anoxic conditions, eutrophication and oligotrophication, suggests that DOC might be a good tool and indicator of global change. [ABSTRACT FROM AUTHOR]

This paper aims at providing insight about bromine (Br) cycle in four Portuguese estuaries: Minho, Lima (in the NW coast) and Sado, Mira (in the SW coast). The focus is on their tidal marsh environments, quite distinct with regard to key biophysicochemical attributes. Regardless of the primary bromide (Br − ) common natural source, i.e., seawater, the NW marshes present relatively higher surface soil/sediment Br concentrations than the ones from SW coast. This happens in close connection with organic matter (OM) content, and is controlled by their main climatic contexts. Yet, the anthropogenic impact on Br concentrations cannot be discarded. Regarding [Br] spatial patterns across the marshes, the results show a general increase from tidal flat toward high marsh. Maxima [Br] occur in the upper driftline zone, at transition from highest low marsh to high marsh, recognized as a privileged setting for OM accumulation. Based on the discovery of OM ubiquitous bromination in marine and transitional environments, it is assumed that this Br occurs mainly as organobromine. Analysis of two dated sediment cores indicates that, despite having the same age (AD ~ 1300), the Caminha salt marsh (Minho estuary) evidences higher Br enrichment than the Casa Branca salt marsh (Mira estuary). This is related to a greater Br storage ability, which is linked to OM build-up and rate dynamics under different climate scenarios. Both cores evidence a fairly similar temporal Br enrichment pattern, and may be interpreted in light of the sun–climate coupling. Thereby, most of the well-known Grand Solar Minima during the Little Ice Age appear to have left an imprint on these marshes, supported by higher [Br] in soils/sediments. Besides climate changes driven by solar activity and impacting marsh Br biogeodynamics, those Br enrichment peaks might also reflect inputs of enhanced volcanic activity covarying with Grand Solar Minima. [ABSTRACT FROM AUTHOR]

The RIHN project “Human impacts on urban subsurface environments” aims to suggest improved development plans of urban centers for human well-being. This will be done by examining reconstructed past changes in urban environments, and by developing integrated nature-social models. Subsurface environmental indicators are developed from the points of view of: (1) human activities; (2) climate change; and (3) character of urban development and social policies. Water, heat, and material environments and transport vectors are being evaluated by a number of different approaches. Some of these include investigating changes in groundwater resources using satellite observations, reconstructing effects of climate change and urbanization using subsurface thermal regimes, and evaluating past contamination patterns from preserved subsurface records. In this overview paper, we describe the current status of urbanization in Asia, subsurface water conditions, material and contaminant transport to surface waters by groundwater, and subsurface thermal anomalies due to the heat island effect. The rapid pace of urbanization in Asia requires that we develop a better understanding of how to deal with environmental impacts, both above and below ground. [Copyright &y& Elsevier]