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Particular Matter (PM) data are the most used for the assessment of air quality, but it is also useful to monitor VOC and CO. The health impact of PM increases with decreasing aerodynamic dimensions, therefore most of the monitoring is aimed at PM10 (fraction of PM with aerodynamic dimensions smaller than 10 µm) and PM2.5 (fraction with aerodynamic dimensions lower than 2.5 µm). Generally, anthropogenic emissions contribute mainly to PM2.5 levels, whereas natural sources can largely affect PM10 concentrations. PM2.5/PM10 ratio can be used as a proxy of the origin (anthropogenic vs natural) of the PM, providing a useful indication about the main sources of PM that characterizes a specific geographical or urban setting. This paper presents the results of the analysis of continuous measurements of PM10 and PM2.5 concentrations at eight stations of the regional air quality monitoring network in Abruzzo (Central Italy), in the period 2017–2018. The application of models based on machine learning technique shows that PM2.5/PM10 ratio can be used to classify PM emissions and to know the nature of the emission source (natural and anthropogenic), under determinate conditions, and properly taking into account the meteorological parameters. [ABSTRACT FROM AUTHOR]